Multifunctional carbon nitride nanoarchitectures for catalysis

P Kumar, G Singh, X Guan, J Lee, R Bahadur… - Chemical Society …, 2023 - pubs.rsc.org
Catalysis is at the heart of modern-day chemical and pharmaceutical industries, and there is
an urgent demand to develop metal-free, high surface area, and efficient catalysts in a …

[PDF][PDF] Control of selectivity in organic synthesis via heterogeneous photocatalysis under visible light

Y Dai, Y Xiong - Nano Res. Energy, 2022 - researchgate.net
Organic synthesis driven by heterogeneous catalysis is a central research theme to both
fundamental research and industrial production of fine chemicals. However, the employment …

Edge modification facilitated heterogenization and exfoliation of two-dimensional nanomaterials for cancer catalytic therapy

L Chen, Z Mao, Y Wang, Y Kang, Y Wang, L Mei… - Science …, 2022 - science.org
The rapid recombination of electron-hole pairs and limited substrates are the most critical
factors astricting the effect of catalytic therapy. Thus, two-dimensional interplanar …

Metal-free photocatalysis: two-dimensional nanomaterial connection toward advanced organic synthesis

C Rosso, G Filippini, A Criado, M Melchionna… - ACS …, 2021 - ACS Publications
Two-dimensional (2D) nanostructures are a frontier in materials chemistry as a result of their
extraordinary properties. Metal-free 2D nanomaterials possess extra appeal due to their …

Carbon vacancies steer the activity in dual Ni carbon nitride photocatalysis

M Marchi, E Raciti, SM Gali, F Piccirilli… - Advanced …, 2023 - Wiley Online Library
The manipulation of carbon nitride (CN) structures is one main avenue to enhance the
activity of CN‐based photocatalysts. Increasing the efficiency of photocatalytic …

Photocatalytic abstraction of hydrogen atoms from water using hydroxylated graphitic carbon nitride for hydrogenative coupling reactions

D Zhang, P Ren, W Liu, Y Li, S Salli, F Han… - Angewandte …, 2022 - Wiley Online Library
Employing pure water, the ultimate green source of hydrogen donor to initiate chemical
reactions that involve a hydrogen atom transfer (HAT) step is fascinating but challenging due …

An integrated carbon nitride‐nickel photocatalyst for the amination of aryl halides using sodium azide

A Vijeta, C Casadevall, E Reisner - Angewandte Chemie, 2022 - Wiley Online Library
The synthesis of primary anilines via sustainable methods remains a challenge in organic
synthesis. We report a photocatalytic protocol for the selective synthesis of primary anilines …

Singlet‐Triplet Energy Inversion in Carbon Nitride Photocatalysts

A Actis, M Melchionna, G Filippini… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Time‐resolved EPR (TR‐EPR) demonstrates the formation of well‐defined spin
triplet excitons in carbon nitride. This permits to experimentally probe the extent of the triplet …

Radical perfluoroalkylation of aliphatic substrates

DE Yerien, S Barata-Vallejo, A Postigo - ACS Catalysis, 2023 - ACS Publications
A selection of perfluoroalkylation reactions of aliphatic substrates that display
methodological and synthetic amplitude will be studied, giving examples of their …

Morphology and Light‐Dependent Spatial Distribution of Spin Defects in Carbon Nitride

A Actis, M Melchionna, G Filippini… - Angewandte Chemie …, 2022 - Wiley Online Library
Carbon nitride (CN) is a heterogeneous photocatalyst that combines good structural
properties and a broad scope. The photocatalytic efficiency of CN is associated with the …