Control of Selectivity in Homogeneous Catalysis through Noncovalent Interactions

KT Mahmudov, AJL Pombeiro - Chemistry–A European …, 2023 - Wiley Online Library
Abstract The regio‐, site‐, stereo‐or chemoselective homogeneous catalytic transformations
are extremely important for the growth/success of the current chemical industry. Based on …

Elaborating E/Z‐Geometry of Alkenes via Cage‐Confined Arylation Catalysis of Terminal Olefins

Y Wang, J Chen, J Yang, Z Jiao… - Angewandte Chemie …, 2023 - Wiley Online Library
A visible light photosensitizing metal‐organic cage is applied as an artificial supramolecular
reactor to control the reaction of aryl radicals with terminal olefins under green light/solvent …

Amide-functionalized organic cationic polymers toward enhanced catalytic performance for conversion of CO2 into cyclic carbonates

YL Wan, L Wang, L Wen - Journal of CO2 Utilization, 2022 - Elsevier
Developing highly efficient, cost-effective and robust heterogeneous catalysts for carbon
dioxide (CO 2) fixation into valuable chemicals plays an essential role in carbon emissions …

Non‐Covalent Interaction‐Controlled Site‐Selective C− H Transformations

Y Kuninobu - The Chemical Record, 2023 - Wiley Online Library
Site‐selective C− H transformations are important to obtain desired compounds as single
products in a highly efficient manner. However, it is generally difficult to achieve such …

[HTML][HTML] Site-selective methylene C–H oxidation of an alkyl diamine enabled by supramolecular recognition using a bioinspired manganese catalyst

A Vicens, L Vicens, G Olivo, O Lanzalunga… - Faraday …, 2023 - pubs.rsc.org
Site-selective oxidation of aliphatic C–H bonds is a powerful synthetic tool because it
enables rapid build-up of product complexity and diversity from simple precursors. Besides …

The strange case of metal coordination in disubstituted-biquinolines: competition between ligands and formation of a hybrid organic/inorganic Cu (II)/Cu (I) ternary …

F Scarpelli, M La Deda, N Godbert… - Journal of …, 2022 - Taylor & Francis
The synthesis of a new Cu (II) derivative,[(biq-OH) CuCl2],(4, 4-bis (hydroxymethyl)-2, 2-
biquinoline (biq-OH)), and its reaction with potassium tropolonate (KTrop) is herein reported …

From Data to Chemistry: Revealing Causality and Reaction Coordinates through Interpretable Machine Learning in Supramolecular Transition Metal Catalysis

RA Talmazan, J Gamper, I Castillo, TS Hofer… - 2024 - chemrxiv.org
Supramolecular transition metal catalysts with tailored reaction environments allow for the
usage of abundant 3d metals as catalytic centres, leading to more sustainable chemical …