Electrochemistry, which employs electrons as reagents and avoids the use of traditional
redox reagents, becomes a powerful tool in oxidative dehydrogenation cross-coupling …

This Perspective illustrates the defining characteristics of free radical chemistry, beginning
with its rich and storied history. Studies from our laboratory are discussed along with recent …

Herein, we develop a new approach to directly access architecturally complex polycyclic
indolines from readily available indoles and bicyclo [1.1. 0] butanes (BCBs) through formal …

Covering: 2000 up to 2019. Catalytic asymmetric dearomatization (CADA) reactions have
witnessed considerable development in recent years. As the most extensively studied sub …

Conspectus The monoterpene indole alkaloids, containing over 3000 known members and
more than 40 structural types, represent one of the largest natural product families that have …

Catalytic asymmetric dearomatization (CADA) reactions offer an efficient strategy for directly
converting aromatic compounds into chiral cyclic molecules. Cascade dearomative …

This work illustrates the reductive coupling of electron-rich aryl halides with tertiary alkyl
halides under Ni-catalyzed cross-electrophile coupling conditions, which offers an efficient …

The axially chiral indole-aryl motifs are present in natural products and biologically active
compounds as well as in chiral ligands. Atroposelective indole formation is an efficient …

Visible-light-induced cycloaddition reactions initiated via energy-transfer processes have
recently evolved as powerful methods for the construction of strained cyclic molecules that …

Transition metal-catalyzed cyclization reactions of unsaturated substrates have become one
of the most important and useful methodologies for the preparation of heterocycles. To this …