Understanding the unceasing evolution of Co (II) based single-ion magnets
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …
Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
Unraveling the contributions to spin–lattice relaxation in kramers single-molecule magnets
The study of how spin interacts with lattice vibrations and relaxes to equilibrium provides
unique insights into its chemical environment and the relation between electronic structure …
unique insights into its chemical environment and the relation between electronic structure …
[HTML][HTML] Single-ion anisotropy and exchange coupling in cobalt (II)-radical complexes: insights from magnetic and ab initio studies
GK Gransbury, ME Boulon, RA Mole, RW Gable… - Chemical …, 2019 - pubs.rsc.org
The concurrent effects of single-ion anisotropy and exchange interactions on the electronic
structure and magnetization dynamics have been analyzed for a cobalt (II)-semiquinonate …
structure and magnetization dynamics have been analyzed for a cobalt (II)-semiquinonate …
Enhanced Heterogeneous Catalytic Activity of Peroxymonosulfate for Rhodamine B Degradation via a CoII-Based Metal–Organic Framework
RJ Zhang, BL Chai, H Xu, TF Zheng, ZH Zhu… - Inorganic …, 2023 - ACS Publications
A stable metal–organic framework with the formula {[Co (BBZB)(IPA)]· H2O} n (JXUST-23,
BBZB= 4, 7-bis (1 H-benzimidazole-1-yl)-2, 1, 3-benzothiadiazole and H2IPA= isophthalic …
BBZB= 4, 7-bis (1 H-benzimidazole-1-yl)-2, 1, 3-benzothiadiazole and H2IPA= isophthalic …
Fine‐Tuning of Structural Distortion and Magnetic Anisotropy by Organosulfonates in Octahedral Cobalt (II) Complexes
D Shao, FX Xu, L Yin, HQ Li, YC Sun… - Chinese Journal of …, 2022 - Wiley Online Library
Comprehensive Summary Precise modulation of the magnetic anisotropy of metal ions
remains highly important for the development of high–performance single‐molecule …
remains highly important for the development of high–performance single‐molecule …
Substituted versus naked thiourea ligand containing pseudotetrahedral Cobalt (II) complexes: A comparative study on its magnetization relaxation dynamics …
A series of mononuclear tetrahedral cobalt (II) complexes with the general molecular formula
[Co (L1) 2X2][where L1= tetramethylthiourea ([(CH3) 2N] 2C═ S) and X= Cl (1), Br (2), and I …
[Co (L1) 2X2][where L1= tetramethylthiourea ([(CH3) 2N] 2C═ S) and X= Cl (1), Br (2), and I …
Field-induced mononuclear cobalt (II) single-molecule magnet (SMM) based on a benzothiadiazole-ortho-vanillin ligand
A unique π-conjugated benzothiadiazole-ortho-vanillin ligand (HL), characterized by single
crystal X-ray diffraction and DFT calculations, has been prepared by condensation between …
crystal X-ray diffraction and DFT calculations, has been prepared by condensation between …
Slow magnetic relaxation triggered by a structural phase transition in long-chain-alkylated cobalt (II) single-ion magnets
F Kobayashi, R Ohtani, M Nakamura… - Inorganic …, 2019 - ACS Publications
The behavior of single-ion magnets (SIMs) that reflects large distortions of their coordination
environments caused by the packing of long alkyl chains for two Co (II) complexes of the …
environments caused by the packing of long alkyl chains for two Co (II) complexes of the …
Slow relaxation of magnetization in a bis-mer-tridentate octahedral Co (II) complex
Reaction of a rigid tridentate ligand o-[(1H-imidazol-2-yl) methylideneamino] phenol (2-
H2imap) with Co (ClO4) 2 in the presence of NaN3, or Co (NO3) 2 without a base yields …
H2imap) with Co (ClO4) 2 in the presence of NaN3, or Co (NO3) 2 without a base yields …