In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

Synthetic organic chemistry experienced a significant advance in the last quarter of the 20th
century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility …

Mechanochemical synthesis with transition-metal catalysts has attracted significant attention
because of its numerous advantages, including reduced solvent waste, shorter reaction …

Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

Activation of aryl chlorides in cross-coupling reactions is a long-standing challenge in
organic synthesis that is of great interest to industry. Ultrasmall (< 3 nm), atomically precise …

Some of the most prominent and promising catalysts in organic synthesis for the requisite
construction of C–C and C–N bonds are palladium (Pd) catalysts, which play a pivotal role in …

Magnetic stir bars are routinely used by every chemist doing synthetic or catalytic
transformations in solution. Each bar lasts for months or years, as the regular PTFE …

Tellurium chemistry has not evolved significantly and there are only a handful of complexes
of metals with organotellurium ligands and nanosized metal tellurides that have been …