The appearance of ferrocene in the middle of the 20th century has revolutionized
organometallic chemistry and is now providing applications in areas as varied and …

In mixed-valence (MV) systems essentially identical, more or less electronically coupled,
redox centres are brought into formally different oxidation states by removal or addition of an …

We report a series of ferrocene-based derivatives and their corresponding oxidized forms in
which the introduction of simple electron donating groups like methyl or tert-butyl units on …

Abstract Whilst 2‐or 5‐OMe groups on the bridging phenylene ring in [{Cp*(dppe) RuC≡ C}
2 (μ‐1, 3‐C6H4)]+ have little influence on the electronic structure of this weakly coupled …

This review summarizes the electronic coupling studies in mixed-valence or donor–acceptor-
type complexes containing one or two cyclometalated ruthenium redox sites. Basic electron …

Recent developments of single‐molecule conductance measurements allow us to
understand fundamental conducting properties of molecular wires. While a wide variety of …

Recent evolutions, essentially in the last 15 years, are reviewed in the field of molecular
mixed‐valent compounds and their properties. The considered systems are of the type Mn …

Metal complexes in molecular junctions - Dalton Transactions (RSC Publishing) DOI:10.1039/C3DT51487K
Royal Society of Chemistry View PDF VersionPrevious ArticleNext Article DOI: 10.1039/C3DT51487K …

Electronic communication through molecular bridges is important for different types of
experiments, such as single-molecule conductance, electron transfer, superexchange spin …

The heterometallic complexes trans‐[Cp (dppe) FeNCRu (o‐bpy) CNFe (dppe) Cp][PF6] n (1
[PF6] n, n= 2, 3, 4; o‐bpy= 1, 2‐bis (2, 2′‐bipyridyl‐6‐yl) ethane, dppe= 1, 2‐bis …