Recent advances in β-L-rhamnosylation

D Rai, SS Kulkarni - Organic & Biomolecular Chemistry, 2020 - pubs.rsc.org
L-Rhamnose forms the key components of important antigenic oligo-and polysaccharides of
a variety of pathogens. Obtaining 1, 2-cis stereoselectivity in the glycosylation of L …

Stereoselective β-mannosylations and β-rhamnosylations from glycosyl hemiacetals mediated by lithium iodide

I Pongener, DA Pepe, JJ Ruddy, EM McGarrigle - Chemical Science, 2021 - pubs.rsc.org
Stereoselective β-mannosylation is one of the most challenging problems in the synthesis of
oligosaccharides. Herein, a highly selective synthesis of β-mannosides and β-rhamnosides …

GRASS: semi-automated NMR-based structure elucidation of saccharides

RR Kapaev, PV Toukach - Bioinformatics, 2018 - academic.oup.com
Motivation Carbohydrates play crucial roles in various biochemical processes and are useful
for developing drugs and vaccines. However, in case of carbohydrates, the primary structure …

Synthesis and Structural Characteristics of all Mono- and Difluorinated 4,6-Dideoxy-d-xylo-hexopyranoses

DE Wheatley, CQ Fontenelle, R Kuppala… - The Journal of …, 2021 - ACS Publications
Protein–carbohydrate interactions are implicated in many biochemical/biological processes
that are fundamental to life and to human health. Fluorinated carbohydrate analogues play …

Total Synthesis of Trisaccharide Repeating Unit of O-Specific Polysaccharide of Pseudomonas fluorescens BIM B-582

A Behera, D Rai, D Kushwaha, SS Kulkarni - Organic letters, 2018 - ACS Publications
The first total synthesis of the trisaccharide repeating unit of the O-specific polysaccharide of
Pseudomonas fluorescens BIM B-582 is reported. This efficient synthesis involves …

Extraction and structural profiling of polysaccharides from Rehmannia glutinosa and anti-inflammatory action via the NF-κB/IκBα pathway

M Xie, J Cai, X Zhong, J Liang, S Liang, M Xian… - Industrial Crops and …, 2024 - Elsevier
Rehmannia glutinosa Libosch is a useful crop for both industrial and medical use.
Polysaccharide is one of the rich components, while its separation, purification and structural …

Synthesis of 4-deoxy pyranosides via catalyst-controlled site-selective toluoylation of abundant sugars

M Yanagi, Y Ueda, R Ninomiya, A Imayoshi… - Organic …, 2019 - ACS Publications
Synthesis of 4-Deoxy Pyranosides via Catalyst-Controlled Site-Selective Toluoylation of
Abundant Sugars | Organic Letters ACS ACS Publications C&EN CAS Find my institution Blank …

[HTML][HTML] Interactions of lipopolysaccharide with lipid membranes, raft models—a solid state NMR study

F Ciesielski, DC Griffin, M Rittig, I Moriyón… - Biochimica et Biophysica …, 2013 - Elsevier
Lipopolysaccharide (LPS) is a major component of the external leaflet of bacterial outer
membranes, key pro-inflammatory factor and an important mediator of host–pathogen …

[HTML][HTML] Improved Synthesis of Sulfur-Containing Glycosides by Suppressing Thioacetyl Migration

T Luo, Y Zhang, J Xi, Y Lu, H Dong - Frontiers in Chemistry, 2020 - frontiersin.org
Complex mixtures were often observed when we attempted to synthesize 4-thio-and 2, 4-
dithio-glycoside derivatives by double parallel and double serial inversion, thus leading to …

Secondary metabolites from Valeriana jatamansi with their anti-inflammatory activity

LH Tram, N Van Thong, LT Thuy, NT Anh… - Natural Product …, 2021 - Taylor & Francis
Valeriana jatamansi is hired as multiple remedies for treatment of insomnia, blood and
circulatory disorders, asthma, dry cough, jaundice, seminal weakness, cardiac debility, and …