Advances in chemistry of N-heterocyclic carbene boryl radicals

T Taniguchi - Chemical Society Reviews, 2021 - pubs.rsc.org
Boron-centred radicals (boryl radicals) are potential and attractive species in main group
chemistry and synthetic chemistry. Recently, the development of boron compounds ligated …

Photopolymerization in dispersed systems

F Jasinski, PB Zetterlund, AM Braun… - Progress in Polymer …, 2018 - Elsevier
Zero-VOC technologies combining ecological and economic efficiency are destined to
occupy a growing place in the polymer economy. Today, Polymerization in dispersed …

Carbon dots as a promising green photocatalyst for free radical and ATRP‐based radical photopolymerization with blue LEDs

C Kütahya, P Wang, S Li, S Liu, J Li… - Angewandte Chemie …, 2020 - Wiley Online Library
Carbon dots (CDs) have been used for the first time as a sensitizer to initiate and activate
free radical and controlled radical polymerization, respectively, based on an ATRP protocol …

A general photo-induced wide-scope regioselective hydroboration of alkenes without using a photocatalyst or an external initiator

YQ Miao, XY Li, QJ Pan, Y Ma, JX Kang, YN Ma… - Green …, 2022 - pubs.rsc.org
Despite the recent development of boryl radical reactions, current methods to generate them
by relying on photocatalysts or radical initiators cause contamination of the reaction. Herein …

Amphiphilic gemini iridium (III) complex as a mitochondria-targeted theranostic agent for tumor imaging and photodynamic therapy

S Yi, Z Lu, J Zhang, J Wang, Z Xie… - ACS applied materials & …, 2019 - ACS Publications
Clinical diagnostics and therapeutics of tumors are significantly benefitted by the
development of multifunctional theranostic agents, which integrate tumor targeting, imaging …

[HTML][HTML] Visible-light induced emulsion photopolymerization with carbon nitride as a stabilizer and photoinitiator

Q Cao, T Heil, B Kumru, M Antonietti… - Polymer Chemistry, 2019 - pubs.rsc.org
Photopolymerization is a common method in the synthesis of polymers with various
applications. Herein, a simple and effective route for surfactant-free emulsion …

Enzyme‐PISA: An Efficient Method for Preparing Well‐Defined Polymer Nano‐Objects under Mild Conditions

J Tan, Q Xu, X Li, J He, Y Zhang, X Dai… - Macromolecular …, 2018 - Wiley Online Library
Enzyme catalysis is a mild, efficient, and selective technique that has many applications in
organic synthesis as well as polymer synthesis. Here, a novel enzyme‐catalysis‐induced …

[HTML][HTML] New horizons for carbon dots: quantum nano-photoinitiating catalysts for cationic photopolymerization and three-dimensional (3D) printing under visible light

W Tomal, T Świergosz, M Pilch, W Kasprzyk… - Polymer Chemistry, 2021 - pubs.rsc.org
Herein, the application of various citric acid-based carbon dots (CDs) as efficient
photosensitizers of iodonium salts in initiating the light-induced cationic polymerization …

Switchable Access to Mono‐and Di‐Alkylated Boranes via Visible‐Light‐Induced Hydroboration of Alkenes with NHC‐Borane

X Wu, Y Wang, MX Zhou, Z Chen… - Advanced Synthesis …, 2023 - Wiley Online Library
A photo‐induced metal‐free radical hydroboration of various styrenes with NHC‐borane has
been developed, which can provide mono‐and di‐alkylated boranes in a selective manner …

Acridine Orange Hemi(Zinc Chloride) Salt as a Lewis Acid‐Photoredox Hybrid Catalyst for the Generation of α‐Carbonyl Radicals

S Das, T Mandal, S De Sarkar - Advanced Synthesis & …, 2022 - Wiley Online Library
A readily accessible organic‐inorganic hybrid catalyst is reported for the reductive
fragmentation of α‐halocarbonyl compounds. The robust hybrid catalyst is a self‐stabilizing …