Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects
NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
Nanoconfinement and mass transport in metal–organic frameworks
CH Sharp, BC Bukowski, H Li, EM Johnson… - Chemical Society …, 2021 - pubs.rsc.org
The ubiquity of metal–organic frameworks in recent scientific literature underscores their
highly versatile nature. MOFs have been developed for use in a wide array of applications …
highly versatile nature. MOFs have been developed for use in a wide array of applications …
Conceptual and practical aspects of metal–organic frameworks for solid–gas reactions
The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
Endohedrally functionalized metal–organic cage-cross-linked polymer gels as modular heterogeneous catalysts
The immobilization of homogeneous catalysts onto supports to improve recyclability while
maintaining catalytic efficiency is often a trial-and-error process limited by poor control of the …
maintaining catalytic efficiency is often a trial-and-error process limited by poor control of the …
Single Metal–Organic Cage Decorated with an Ir(III) Complex for CO2 Photoreduction
X Qi, R Zhong, M Chen, C Sun, S You, J Gu… - ACS …, 2021 - ACS Publications
CO2 photoreduction is a promising avenue to alleviate climate change and energy shortage,
and highly active and selective photocatalysts have been pursued. Discrete metal–organic …
and highly active and selective photocatalysts have been pursued. Discrete metal–organic …
Molecular Co-Catalyst Confined within a Metallacage for Enhanced Photocatalytic CO2 Reduction
D Liu, H Ma, C Zhu, F Qiu, W Yu, LL Ma… - Journal of the …, 2024 - ACS Publications
The construction of structurally well-defined supramolecular hosts to accommodate
catalytically active species within a cavity is a promising way to address catalyst …
catalytically active species within a cavity is a promising way to address catalyst …
[HTML][HTML] Mass transport effects in gas-phase selective hydrogenation of 1, 3-butadiene over supported Pd
OEB Corstius, M Kikkert, ST Roberts… - Reaction Chemistry & …, 2024 - pubs.rsc.org
Selective hydrogenation reactions are essential in the purification of light olefins by removal
of polyunsaturated hydrocarbon impurities (alkynes/alkadienes). Pd-based catalysts are …
of polyunsaturated hydrocarbon impurities (alkynes/alkadienes). Pd-based catalysts are …
Facile immobilization of PNNN P-Pd pincer complexes in MFU-4 l-OH and the effects of guest loading on Lewis acid catalytic activity
JS Hilliard, CR Wade - Dalton Transactions, 2023 - pubs.rsc.org
A palladium diphosphine pincer complex H3 (PNNNP-PdI) has been encapsulated in the
benzotriazolate metal-organic framework MFU-4l-OH ([Zn5 (OH) 4 (btdd) 3], btdd2−= bis (1 …
benzotriazolate metal-organic framework MFU-4l-OH ([Zn5 (OH) 4 (btdd) 3], btdd2−= bis (1 …