Isoprene emissions in Africa inferred from OMI observations of formaldehyde columns

EA Marais, DJ Jacob, TP Kurosu… - Atmospheric …, 2012 - acp.copernicus.org
We use 2005–2009 satellite observations of formaldehyde (HCHO) columns from the OMI
instrument to infer biogenic isoprene emissions at monthly 1× 1° resolution over the African …

Insights into hydroxyl measurements and atmospheric oxidation in a California forest

J Mao, X Ren, L Zhang, DM Van Duin… - Atmospheric …, 2012 - acp.copernicus.org
The understanding of oxidation in forest atmospheres is being challenged by measurements
of unexpectedly large amounts of hydroxyl (OH). A significant number of these OH …

Experimental evidence for efficient hydroxyl radical regeneration in isoprene oxidation

H Fuchs, A Hofzumahaus, F Rohrer, B Bohn… - Nature …, 2013 - nature.com
Most pollutants in the Earth's atmosphere are removed by oxidation with highly reactive
hydroxyl radicals. Field measurements have revealed much higher concentrations of …

Atmospheric Fate of Methacrolein. 1. Peroxy Radical Isomerization Following Addition of OH and O2

JD Crounse, HC Knap, KB Ørnsø… - The Journal of …, 2012 - ACS Publications
Peroxy radicals formed by addition of OH and O2 to the olefinic carbon atoms in
methacrolein react with NO to form methacrolein hydroxy nitrate and hydroxyacetone. We …

Quantifying the magnitude of a missing hydroxyl radical source in a tropical rainforest

LK Whalley, PM Edwards, KL Furneaux… - Atmospheric …, 2011 - acp.copernicus.org
The lifetime of methane is controlled to a very large extent by the abundance of the OH
radical. The tropics are a key region for methane removal, with oxidation in the lower tropical …

Measurements of hydroxyl and hydroperoxy radicals during CalNex‐LA: Model comparisons and radical budgets

SM Griffith, RF Hansen, S Dusanter… - Journal of …, 2016 - Wiley Online Library
Measurements of hydroxyl (OH) and hydroperoxy (HO2*) radical concentrations were made
at the Pasadena ground site during the CalNex‐LA 2010 campaign using the laser‐induced …

HOx radical regeneration in isoprene oxidation via peroxy radical isomerisations. II: experimental evidence and global impact

J Peeters, JF Müller - Physical Chemistry Chemical Physics, 2010 - pubs.rsc.org
A consistent body of experimental evidence from work of other groups is presented in
support of the novel, theoretically based, isoprene oxidation mechanism we recently …

Key chemical NOx sink uncertainties and how they influence top-down emissions of nitrogen oxides

T Stavrakou, JF Müller, KF Boersma… - Atmospheric …, 2013 - acp.copernicus.org
Triggered by recent developments from laboratory and field studies regarding major NO x
sink pathways in the troposphere, this study evaluates the influence of chemical …

Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR

A Novelli, L Vereecken, B Bohn, HP Dorn… - Atmospheric …, 2020 - acp.copernicus.org
Theoretical, laboratory, and chamber studies have shown fast regeneration of the hydroxyl
radical (OH) in the photochemistry of isoprene, largely due to unimolecular reactions which …

Detection of HO2 by laser-induced fluorescence: calibration and interferences from RO2 radicals

H Fuchs, B Bohn, A Hofzumahaus… - Atmospheric …, 2011 - amt.copernicus.org
HO 2 concentration measurements are widely accomplished by chemical conversion of HO
2 to OH including reaction with NO and subsequent detection of OH by laser-induced …