Haloferrocenes: syntheses and selected reactions

H Butenschön - Synthesis, 2018 - thieme-connect.com
Although haloferrocenes constitute important starting materials for many ferrocene-derived
products with importance in a variety of fields such as materials science, medicinal chemistry …

[HTML][HTML] Tuning the thermoelectrical properties of anthracene-based self-assembled monolayers

A Ismael, X Wang, TLR Bennett, LA Wilkinson… - Chemical …, 2020 - pubs.rsc.org
It is known that the electrical conductance of single molecules can be controlled in a
deterministic manner by chemically varying their anchor groups to external electrodes. Here …

Scale-up of room-temperature constructive quantum interference from single molecules to self-assembled molecular-electronic films

X Wang, TLR Bennett, A Ismael… - Journal of the …, 2020 - ACS Publications
The realization of self-assembled molecular-electronic films, whose room-temperature
transport properties are controlled by quantum interference (QI), is an essential step in the …

Electronic structures of transition metal sandwich complexes revisited by high-resolution laser spectroscopy coupled with DFT

SY Ketkov - Mendeleev Communications, 2024 - Elsevier
Laser photoionization spectroscopy provides extremely high accuracy in determining
ionization energies of jet-cooled bisarene complexes, metallocenes and mixed sandwich …

The unusual redox properties of fluoroferrocenes revealed through a comprehensive study of the haloferrocenes

MS Inkpen, S Du, M Hildebrand, AJP White… - …, 2015 - ACS Publications
We report the synthesis and full characterization of the entire haloferrocene (FcX) and 1, 1′-
dihaloferrocene (fcX2) series (X= I, Br, Cl, F; Fc= ferrocenyl, fc= ferrocene-1, 1′-diyl) …

[HTML][HTML] Laser spectroscopic and computational insights into unexpected structural behaviours of sandwich complexes upon ionization

SY Ketkov, SY Tzeng, EA Rychagova, GV Markin… - Dalton …, 2021 - pubs.rsc.org
Transition-metal sandwich complexes play key roles in various fields such as fundamental
and applied chemistry; many of their unique properties arise from their ability to form stable …

[HTML][HTML] Ionization of Decamethylmanganocene: Insights from the DFT-Assisted Laser Spectroscopy

S Ketkov, SY Tzeng, E Rychagova, WB Tzeng - Molecules, 2022 - mdpi.com
Metallocenes represent one of the most important classes of organometallics with wide
prospects for practical use in various fields of chemistry, materials science, molecular …

[HTML][HTML] A convenient synthesis of ferrocene-(ethynylphenyl) thioacetates

TLR Bennett, NJ Long - Dalton Transactions, 2023 - pubs.rsc.org
Ferrocene is popular within the field of molecular electronics due to its well-defined
electronic properties. However, where the conductance of highly-conjugated …

[HTML][HTML] Substituent effects on the electronic structures of sandwich compounds: new understandings provided by DFT-assisted laser ionization spectroscopy of …

S Ketkov - Dalton Transactions, 2020 - pubs.rsc.org
Recent advances on substituent effects in transition metal bisarene complexes studied with
high-resolution threshold ionization spectroscopy are reviewed to demonstrate new aspects …

Deltoid versus Rhomboid: Controlling the Shape of Bis-ferrocene Macrocycles by the Bulkiness of the Substituents

V Hoffmann, L Le Pleux, D Häussinger… - …, 2017 - ACS Publications
Precise structural control of heteroannularly disubstituted ferrocene (Fc) structures is very
challenging as the high rotational mobility of the Fc unit allows a large conformational …