Site-selective C (sp3)-H Functionalization of Primary Aliphatic Amines

Y Tao, K Guo, H Chen, G Yan, M Guo - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
The CH bond functionalization represents one of the most efficient and straightforward
strategies to diversify the existing molecules. It is the most challenging task to achieve the …

Unveiling the Mechanistic Role of Chiral Palladacycles in Pd(II)‐Catalyzed Enantioselective C(sp3)−H Functionalization

CH Yuan, XX Wang, K Huang… - Angewandte Chemie …, 2024 - Wiley Online Library
Palladium‐catalyzed enantioselective C (sp3)− H functionalization reactions has attracted
considerable attention due to its ability for the synthesis of enantiomerically enriched …

Directed C(sp3)-H Arylation of Free α-Aminophosphonates: Dual Models Exploration via Palladium Catalysis

LN Yi, T Zhao, J Bu, J Long, Q Yang - Organic Letters, 2024 - ACS Publications
In this report, we present the dual activation models for transient directing group-directed
and amino-self-directed Pd-catalyzed α-aminophosphonate side-chain C (sp3)-H arylation …