The metal-hydride hydrogen atom transfer (MHAT) reaction plays an important role in the
field of natural product synthesis. MHAT, as a powerful method, has been employed by …

Developed synthetic strategies for abietane and icetexane diterpenoids during 2010-present
are described in this review. To date, the [6–6–6]-and [6–7–6]-tricyclic skeletons of …

A hydrogen atom transfer (HAT)-initiated Dowd–Beckwith rearrangement reaction was
developed, which enables the efficient assembly of diversely functionalized polyquinane …

An efficient and scalable total synthesis of (−)-triptonide is accomplished based on a metal-
catalyzed hydrogen atom transfer (MHAT)-initiated radical cyclization. During the …

A unified strategy toward asymmetric divergent syntheses of nine C8-ethano-bridged
diterpenoids A1–A9 (candol A, powerol, sicanadiol, epi-candol A, atisirene, ent-atisan-16α …

The first asymmetric total synthesis of the hexacyclic veatchine-type C20-diterpenoid
alkaloid (−)-garryine is presented. Key steps include a Pd-catalyzed enantioselective Heck …

Intramolecular hydroarylation of alkenes through hydrogen atom transfer (HAT) represents a
robust method to prepare benzo-fused heterocycles. However, the reported methods have …

The asymmetric total synthesis of (−)-retigeranic acid A has been realized. The key features
of the current synthesis include (1) a Pt-catalyzed Conia-ene 5-exo-dig cyclization of …

We achieved a concise total synthesis of salimabromide by using a novel intramolecular
radical cyclization to simultaneously construct the unique benzo-fused [4.3. 1] carbon …

Here, we report a photocatalytic charge-transfer complex (CTC) strategy for one electron
reduction of alkenes using thiolate as a catalytic electron donor. This catalytic CTC system …