[HTML][HTML] Aqueous alteration of silicate glass: state of knowledge and perspectives

S Gin, JM Delaye, F Angeli, S Schuller - npj Materials Degradation, 2021 - nature.com
The question of silicate glass chemical durability is at the heart of many industrial and
environmental issues, with certain glasses, such as bioglasses, needing to transform rapidly …

Recent advances in corrosion science applicable to disposal of high-level nuclear waste

GS Frankel, JD Vienna, J Lian, X Guo, S Gin… - Chemical …, 2021 - ACS Publications
High-level radioactive waste is accumulating at temporary storage locations around the
world and will eventually be placed in deep geological repositories. The waste forms and …

Iodine dissolution mechanisms in high-pressure aluminoborosilicate glasses and their relationship to oxygen speciation

Y Morizet, S Soudani, J Hamon, M Paris, C La… - Journal of Materials …, 2023 - pubs.rsc.org
Incorporation of iodine (I) into high-pressure vitrified glasses appears to be a potential
solution for the immobilization of 129I radioisotopes. Under these conditions, I dissolution is …

Impact of magnesium on the structure of aluminoborosilicate glasses: A solid‐state NMR and Raman spectroscopy study

N Bisbrouck, M Bertani, F Angeli… - Journal of the …, 2021 - Wiley Online Library
Seven magnesium‐containing aluminoborosilicate glasses, with three to five oxides, have
been studied through comprehensive multinuclear solid‐state NMR (11B, 27Al, 29Si, 23Na …

Composition dependence of the atomic structures and properties of sodium aluminosilicate glasses: molecular dynamics simulations with reactive and nonreactive …

J Kalahe, M Ono, S Urata, J Du - The Journal of Physical …, 2022 - ACS Publications
Understanding the composition–structure–property relations of glass materials is essential
for their technological applications. In this study, the structures and properties of a series of …

[HTML][HTML] Effects of irradiation on the mechanisms controlling the residual rate of an alumino-borosilicate glass

S Gin, C Jegou, L Sessegolo, N Bisbrouck… - Npj Materials …, 2022 - nature.com
The alteration of a four-oxide alumino-borosilicate glass close to International Simple Glass
(ISG) was studied in Si saturation conditions at pH 3, pH 7, and pH 9 using solution and post …

Photothermal atomic force microscopy coupled with infrared spectroscopy (AFM-IR) analysis of high extinction coefficient materials: a case study with silica and silicate …

YT Lin, H He, H Kaya, H Liu, D Ngo, NJ Smith… - Analytical …, 2022 - ACS Publications
Photothermal atomic force microscopy coupled with infrared spectroscopy (AFM-IR) brings
significant value as a spatially resolved surface analysis technique for disordered oxide …

Impact of gold ion irradiation on the initial alteration rate of the International Simple Glass

C Gillet, S Szenknect, M Tribet, H Arena… - Journal of Nuclear …, 2024 - Elsevier
This study addresses the impact of 7 MeV Au irradiation on the initial alteration rate of
International Simple Glass (ISG), considered as a reference for nuclear glasses. This …

Effects of vapor hydration and radiation on the leaching behavior of nuclear glass

H Zhang, T Suzuki-Muresan, S Gin, G Blain… - Journal of Nuclear …, 2023 - Elsevier
During the long-term disposal of high-level nuclear waste glass in the geological disposal
facility, the nuclear glass could be exposed to an unsaturated vapor environment prior to the …

[HTML][HTML] On the effect of Al on alumino-borosilicate glass chemical durability

K Damodaran, S Gin, S Narayanasamy… - npj Materials …, 2023 - nature.com
The chemical durability of borosilicate glass used to confine nuclear wastes is known to vary
nonlinearly with their composition, making glass dissolution rate predictions difficult. Here …