Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

In this review, selected recent advances in the preparation and reactivity of aziridines using
modern synthetic approaches are highlighted, while comparing these new strategies with …

C 4-Symmetrical dirhodium (II) tetracarboxylates are highly efficient catalysts for the
asymmetric intermolecular aziridination of substituted alkenes with sulfamates. The reaction …

Conspectus Carbon–nitrogen (C–N) bonds are ubiquitous in pharmaceuticals,
agrochemicals, diverse bioactive natural products, and ligands for transition metal catalysts …

Among the central themes in synthetic chemistry is the establishment of novel strategies that
usher in the development of more efficient and mild reactions and also expand the chemical …

Catalytic carboamination of alkenes is a powerful synthetic tool to access valuable amine
scaffolds from abundant and readily available alkenes. Although a number of synthetic …

Azepanes are important seven‐membered heterocycles, which are present in numerous
natural and synthetic compounds. However, the development of convergent synthetic …

The introduction of nitrogen atoms into small molecules is of fundamental importance and it
is vital that ever more efficient and selective methods for achieving this are developed. With …

Asymmetric C–H amination via nitrene transfer is a powerful tool to prepare enantioenriched
amine precursors from abundant C–H bonds. Herein, we report a regio-and enantioselective …

Enantioselective radical N-heterobicyclization of N-allylsulfamoyl azides has been
developed via metalloradical catalysis (MRC). The Co (II)-based catalytic system can …