Synthesis and glycosidation of anomeric halides: evolution from early studies to modern methods of the 21st century

Y Singh, SA Geringer, AV Demchenko - Chemical reviews, 2022 - ACS Publications
Advances in synthetic carbohydrate chemistry have dramatically improved access to
common glycans. However, many novel methods still fail to adequately address challenges …

Highly Stereoselective Synthesis of Branched Fructooligosaccharides ABW90-1 and ABW50-1 from Achyranthes bidentata with Potent Antiosteoporosis Activities

K Li, B Liu, X Wang, G Xiao - Organic Letters, 2024 - ACS Publications
The branched fructooligosaccharides ABW90-1 and ABW50-1 from Achyranthes bidentata
with potent antiosteoporosis activities have been synthesized for the first time. The synthetic …

A versatile approach to the synthesis of glycans containing mannuronic acid residues

C Alex, S Visansirikul, AV Demchenko - Organic & Biomolecular …, 2021 - pubs.rsc.org
Reported herein is a new method for a highly effective synthesis of β-glycosides from
mannuronic acid donors equipped with the 3-O-picoloyl group. The stereocontrol of …

Iterative Synthesis of Inulin-Type Fructooligosaccharides Enabled by Stereoselective β-d-Fructofuranosylation

LJ Zou, X Yang, XR Zhao, H He, D Zhang… - The Journal of …, 2022 - ACS Publications
Inulin-type fructooligosaccharides (FOSs) constitute an abundant subgroup of fructans with
important biological activities. However, the availability of individual fructooligosaccharides …

Direct synthesis of glycans containing challenging ManNAcA residues

C Alex, AV Demchenko - The Journal of Organic Chemistry, 2021 - ACS Publications
A method for direct, highly stereoselective synthesis of glycans containing β-linked d-
mannosaminuronic acid (ManNAcA) residues is reported herein, among which is the …

[HTML][HTML] Synthesis and glycosidation of building blocks of D-altrosamine

M Novakova, A Das, C Alex, AV Demchenko - Frontiers in Chemistry, 2022 - frontiersin.org
Presented herein is a streamlined synthesis of building blocks of a rare sugar D-altrosamine.
Also investigated was the glycosylation of different glycosyl acceptors with differentially …