Long-range distance determinations in biomacromolecules by EPR spectroscopy
O Schiemann, TF Prisner - Quarterly reviews of biophysics, 2007 - cambridge.org
Electron paramagnetic resonance (EPR) spectroscopy provides a variety of tools to study
structures and structural changes of large biomolecules or complexes thereof. In order to …
structures and structural changes of large biomolecules or complexes thereof. In order to …
Disentangling intricate web of interrelated notions at the interface between the physical (crystal field) Hamiltonians and the effective (spin) Hamiltonians
C Rudowicz, M Karbowiak - Coordination Chemistry Reviews, 2015 - Elsevier
This review provides a summary of distinct Hamiltonians used to describe magnetic and
spectroscopic properties of paramagnetic and magnetic coordination compounds. Based on …
spectroscopic properties of paramagnetic and magnetic coordination compounds. Based on …
Importance of direct spin− spin coupling and spin-flip excitations for the zero-field splittings of transition metal complexes: A case study
F Neese - Journal of the American Chemical Society, 2006 - ACS Publications
This work reports the evaluation of several theoretical approaches to the zero-field splitting
(ZFS) in transition metal complexes. The experimentally well-known complex [Mn (acac) 3] is …
(ZFS) in transition metal complexes. The experimentally well-known complex [Mn (acac) 3] is …
Targeted DNP for biomolecular solid-state NMR
High-field dynamic nuclear polarization is revolutionizing the scope of solid-state NMR with
new applications in surface chemistry, materials science and structural biology. In this …
new applications in surface chemistry, materials science and structural biology. In this …
PELDOR measurements on a nitroxide-labeled Cu (II) porphyrin: orientation selection, spin-density distribution, and conformational flexibility
BE Bode, J Plackmeyer, TF Prisner… - The Journal of …, 2008 - ACS Publications
Metal ions are functionally or structurally important centers in metalloproteins or RNAs,
which makes them interesting targets for spectroscopic investigations. In combination with …
which makes them interesting targets for spectroscopic investigations. In combination with …
Measurement of Angstrom to Nanometer Molecular Distances with 19F Nuclear Spins by EPR/ENDOR Spectroscopy
A Meyer, S Dechert, S Dey… - Angewandte Chemie …, 2020 - Wiley Online Library
Spectroscopic and biophysical methods for structural determination at atomic resolution are
fundamental in studies of biological function. Here we introduce an approach to measure …
fundamental in studies of biological function. Here we introduce an approach to measure …
Hydrogen Bond Network between Amino Acid Radical Intermediates on the Proton-Coupled Electron Transfer Pathway of E. coli α2 Ribonucleotide Reductase
TU Nick, W Lee, S Koßmann, F Neese… - Journal of the …, 2015 - ACS Publications
Ribonucleotide reductases (RNRs) catalyze the conversion of ribonucleotides to
deoxyribonucleotides in all organisms. In all Class Ia RNRs, initiation of nucleotide …
deoxyribonucleotides in all organisms. In all Class Ia RNRs, initiation of nucleotide …
The strength of EPR and ENDOR techniques in revealing structure–function relationships in metalloproteins
S Van Doorslaer, E Vinck - Physical Chemistry Chemical Physics, 2007 - pubs.rsc.org
Recent technological and methodological advances have strongly increased the potential of
electron paramagnetic resonance (EPR) and electron nuclear double resonance (ENDOR) …
electron paramagnetic resonance (EPR) and electron nuclear double resonance (ENDOR) …
High-field/high-frequency EPR spectroscopy on synthetic melanin: On the origin of carbon-centered radicals
Among all the pigments found in nature, melanin has drawn considerable attention for
bioelectronics applications as it contains a set of physicochemical properties such as …
bioelectronics applications as it contains a set of physicochemical properties such as …
Electron spin resonance in emerging spin-driven applications: Fundamentals and future perspectives
Spin, the intrinsic angular momentum of an electron, is increasingly being recognized as a
versatile tool in the development of next-generation technologies, including quantum …
versatile tool in the development of next-generation technologies, including quantum …