Molecular catalysts with diphosphine ligands containing pendant amines

ES Wiedner, AM Appel, S Raugei, WJ Shaw… - Chemical …, 2022 - ACS Publications
Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Hierarchical nanomaterials via biomolecular self-assembly and bioinspiration for energy and environmental applications

C Gong, S Sun, Y Zhang, L Sun, Z Su, A Wu, G Wei - Nanoscale, 2019 - pubs.rsc.org
Bioinspired synthesis offers potential green strategies to build highly complex nanomaterials
by utilizing the unique nanostructures, functions, and properties of biomolecules, in which …

Beyond the active site: the impact of the outer coordination sphere on electrocatalysts for hydrogen production and oxidation

B Ginovska-Pangovska, A Dutta… - Accounts of Chemical …, 2014 - ACS Publications
Conspectus Redox active metalloenzymes play a major role in energy transformation
reactions in biological systems. Examples include formate dehydrogenases, nitrogenases …

Carbon‐Nanotube‐Supported Bio‐Inspired Nickel Catalyst and Its Integration in Hybrid Hydrogen/Air Fuel Cells

S Gentil, N Lalaoui, A Dutta, Y Nedellec… - Angewandte …, 2017 - Wiley Online Library
A biomimetic nickel bis‐diphosphine complex incorporating the amino acid arginine in the
outer coordination sphere was immobilized on modified carbon nanotubes (CNTs) through …

Biological and synthetic template-directed syntheses of mineralized hybrid and inorganic materials

C Wang, K Jiao, J Yan, M Wan, Q Wan… - Progress in Materials …, 2021 - Elsevier
Throughout the course of evolution, organisms have produced biominerals with hierarchical
structures derived from organic templates. Over the last couple of decades, scientists have …

Polymer-encapsulated metal complex catalysts: An emerging and efficient platform for electrochemical CO2 reduction

Y Liu, S Lyu, F Wen, W Nie, S Wang - Journal of Materials Science & …, 2023 - Elsevier
Over the past decade, electrocatalytic reduction of CO 2 has gained substantial attention.
However, hardly any of the previous reviews have focused on the systematic discussion of …

Enzyme-Inspired Synthetic Proton Relays Generate Fast and Acid-Stable Cobalt-Based H2 Production Electrocatalysts

D Dolui, S Khandelwal, A Shaik, D Gaat… - Acs …, 2019 - ACS Publications
Construction of a water-soluble, oxygen-tolerant, and acid-stable synthetic H2 production
catalyst is vital for the development of an economic and user-friendly H2-based renewable …

[HTML][HTML] From protein engineering to artificial enzymes–biological and biomimetic approaches towards sustainable hydrogen production

C Esmieu, P Raleiras, G Berggren - Sustainable Energy & Fuels, 2018 - pubs.rsc.org
Hydrogen gas is used extensively in industry today and is often put forward as a suitable
energy carrier due its high energy density. Currently, the main source of molecular hydrogen …

Artificial hydrogenases: biohybrid and supramolecular systems for catalytic hydrogen production or uptake

G Caserta, S Roy, M Atta, V Artero… - Current Opinion in …, 2015 - Elsevier
Highlights•Active sites of hydrogenases can be synthetically imitated to produce efficient
catalysts.•Maturation and activation of hydrogenases can be achieved with the closest active …