Back to the future of organolanthanide chemistry
At the dawn of the development of structural organometallic chemistry, soon after the
discovery of ferrocene, the description of the LnCp3 complexes, featuring large and mostly …
discovery of ferrocene, the description of the LnCp3 complexes, featuring large and mostly …
Boosting axiality in stable high-coordinate Dy (III) single-molecule magnets
AB Canaj, MK Singh, ER Marti, M Damjanović… - Chemical …, 2019 - pubs.rsc.org
Boosting axiality in stable high-coordinate Dy( iii ) single-molecule magnets - Chemical
Communications (RSC Publishing) DOI:10.1039/C9CC00965E Royal Society of Chemistry …
Communications (RSC Publishing) DOI:10.1039/C9CC00965E Royal Society of Chemistry …
Quantum tunnelling of the magnetisation in single-molecule magnet isotopologue dimers
E Moreno-Pineda, G Taran, W Wernsdorfer… - Chemical …, 2019 - pubs.rsc.org
Quantum tunnelling of the magnetisation plays a major role in the magnetic properties of
lanthanide Single-Molecule Magnets: while it is considered a problem for data storage …
lanthanide Single-Molecule Magnets: while it is considered a problem for data storage …
Dynamic Magnetic Properties of Germole‐ligated Lanthanide Sandwich Complexes
The first germole‐ligated single‐molecule magnets are reported, with contrasting properties
found for the near‐linear sandwich complexes [(η8‐COT) Ln (η5‐CpGe]−, where Ln= Dy …
found for the near‐linear sandwich complexes [(η8‐COT) Ln (η5‐CpGe]−, where Ln= Dy …
Structural and magnetization dynamics of borohydride-bridged rare-earth metallocenium cations
CGT Price, A Mondal, JP Durrant, J Tang… - Inorganic …, 2023 - ACS Publications
The structure and magnetic properties of the bimetallic borohydride-bridged
dysprosocenium compound [{(η5-Cpttt)(η5-CpMe4t) Dy} 2 (μ: κ2: κ2-BH4)]+[B (C6F5) 4]−([3 …
dysprosocenium compound [{(η5-Cpttt)(η5-CpMe4t) Dy} 2 (μ: κ2: κ2-BH4)]+[B (C6F5) 4]−([3 …
Slow magnetic relaxation in a homoaxially phosphine oxide coordinated pentagonal bipyramidal Dy (III) complex
We report the synthesis of [(L) DyIII (Cy3PO) 2]·[BPh4](1-Dy)(where H2L= 2, 6-
diacetylpyridine bis-benzoylhydrazone and Cy= cyclohexyl) which crystallized in the triclinic …
diacetylpyridine bis-benzoylhydrazone and Cy= cyclohexyl) which crystallized in the triclinic …
Heteroleptic Rare-Earth Tris (metallocenes) Containing a Dibenzocyclooctatetraene Dianion
ER Pugliese, F Benner, E Castellanos… - Inorganic …, 2022 - ACS Publications
Isolable heteroleptic tris (metallocenes) containing five-membered and larger rings remain
extremely scarce. The utilization of tripositive rare-earth-metal ions with ionic radii> 1 Å …
extremely scarce. The utilization of tripositive rare-earth-metal ions with ionic radii> 1 Å …
Fulvalene as a platform for the synthesis of a dimetallic dysprosocenium single-molecule magnet
The dinucleating fulvalenyl ligand [1, 1′, 3, 3′-(C5tBu2H2) 2] 2−(Fvtttt) was used to
synthesize the dimetallic dysprosocenium cation [{Dy (η5-Cp*)} 2 (μ-BH4)(η5: η5-Fvtttt)]+(3) …
synthesize the dimetallic dysprosocenium cation [{Dy (η5-Cp*)} 2 (μ-BH4)(η5: η5-Fvtttt)]+(3) …
Understanding electrostatics and covalency effects in highly anisotropic organometallic sandwich dysprosium complexes [Dy (C m R m) 2](where R= H, SiH 3, CH 3 …
In this article, we have thoroughly studied the electronic structure and 4f-ligand covalency of
six mononuclear dysprosium organometallic sandwich complexes [Dy (CmRm) 2] …
six mononuclear dysprosium organometallic sandwich complexes [Dy (CmRm) 2] …
Enhanced single-molecule magnetism in dysprosium complexes of a pristine cyclobutadienyl ligand
JP Durrant, J Tang, A Mansikkamäki… - Chemical …, 2020 - pubs.rsc.org
Intact transfer of the cyclobutadienyl ligand [C4 (SiMe3) 4] 2− to yttrium and dysprosium (M)
produces the half-sandwich complexes [M {η4-C4 (SiMe3) 4}(BH4) 2 (THF)]− as …
produces the half-sandwich complexes [M {η4-C4 (SiMe3) 4}(BH4) 2 (THF)]− as …