Back to the future of organolanthanide chemistry

N Mahieu, J Piątkowski, T Simler, G Nocton - Chemical Science, 2023 - pubs.rsc.org
At the dawn of the development of structural organometallic chemistry, soon after the
discovery of ferrocene, the description of the LnCp3 complexes, featuring large and mostly …

Boosting axiality in stable high-coordinate Dy (III) single-molecule magnets

AB Canaj, MK Singh, ER Marti, M Damjanović… - Chemical …, 2019 - pubs.rsc.org
Boosting axiality in stable high-coordinate Dy( iii ) single-molecule magnets - Chemical
Communications (RSC Publishing) DOI:10.1039/C9CC00965E Royal Society of Chemistry …

Quantum tunnelling of the magnetisation in single-molecule magnet isotopologue dimers

E Moreno-Pineda, G Taran, W Wernsdorfer… - Chemical …, 2019 - pubs.rsc.org
Quantum tunnelling of the magnetisation plays a major role in the magnetic properties of
lanthanide Single-Molecule Magnets: while it is considered a problem for data storage …

Dynamic Magnetic Properties of Germole‐ligated Lanthanide Sandwich Complexes

S De, A Mondal, ZY Ruan, ML Tong… - … –A European Journal, 2023 - Wiley Online Library
The first germole‐ligated single‐molecule magnets are reported, with contrasting properties
found for the near‐linear sandwich complexes [(η8‐COT) Ln (η5‐CpGe]−, where Ln= Dy …

Structural and magnetization dynamics of borohydride-bridged rare-earth metallocenium cations

CGT Price, A Mondal, JP Durrant, J Tang… - Inorganic …, 2023 - ACS Publications
The structure and magnetic properties of the bimetallic borohydride-bridged
dysprosocenium compound [{(η5-Cpttt)(η5-CpMe4t) Dy} 2 (μ: κ2: κ2-BH4)]+[B (C6F5) 4]−([3 …

Slow magnetic relaxation in a homoaxially phosphine oxide coordinated pentagonal bipyramidal Dy (III) complex

P Kalita, N Ahmed, S Moorthy, V Béreau, AK Bar… - Dalton …, 2023 - pubs.rsc.org
We report the synthesis of [(L) DyIII (Cy3PO) 2]·[BPh4](1-Dy)(where H2L= 2, 6-
diacetylpyridine bis-benzoylhydrazone and Cy= cyclohexyl) which crystallized in the triclinic …

Heteroleptic Rare-Earth Tris (metallocenes) Containing a Dibenzocyclooctatetraene Dianion

ER Pugliese, F Benner, E Castellanos… - Inorganic …, 2022 - ACS Publications
Isolable heteroleptic tris (metallocenes) containing five-membered and larger rings remain
extremely scarce. The utilization of tripositive rare-earth-metal ions with ionic radii> 1 Å …

Fulvalene as a platform for the synthesis of a dimetallic dysprosocenium single-molecule magnet

M He, FS Guo, J Tang, A Mansikkamäki… - Chemical Science, 2020 - pubs.rsc.org
The dinucleating fulvalenyl ligand [1, 1′, 3, 3′-(C5tBu2H2) 2] 2−(Fvtttt) was used to
synthesize the dimetallic dysprosocenium cation [{Dy (η5-Cp*)} 2 (μ-BH4)(η5: η5-Fvtttt)]+(3) …

Understanding electrostatics and covalency effects in highly anisotropic organometallic sandwich dysprosium complexes [Dy (C m R m) 2](where R= H, SiH 3, CH 3 …

I Tarannum, S Moorthy, SK Singh - Dalton Transactions, 2023 - pubs.rsc.org
In this article, we have thoroughly studied the electronic structure and 4f-ligand covalency of
six mononuclear dysprosium organometallic sandwich complexes [Dy (CmRm) 2] …

Enhanced single-molecule magnetism in dysprosium complexes of a pristine cyclobutadienyl ligand

JP Durrant, J Tang, A Mansikkamäki… - Chemical …, 2020 - pubs.rsc.org
Intact transfer of the cyclobutadienyl ligand [C4 (SiMe3) 4] 2− to yttrium and dysprosium (M)
produces the half-sandwich complexes [M {η4-C4 (SiMe3) 4}(BH4) 2 (THF)]− as …