The tailoring of the coordination chemistry around f-element centers is a crucial step for the
development of compounds with slow magnetic relaxation, including single-molecule …

Three di-nuclear DyIII complexes [Dy2 (H2L) 2 (tfa)]· Cl· 3DMF (1),[Dy2 (H2L) 2
(MeO)(SCN)]· MeOH (2) and [Dy2 (H2L) 2 (MeOH) Cl]· Cl· 2MeOH (3) were synthesized and …

The dimetallic fulvalene-bridged dysprosium complex [{Dy (Cp*)(μ-BH4)} 2 (Fvtttt)](1, Cp*=
C5Me5) is converted into the trimetallic borohydride-bridged species [{Dy (Cp*)(Fvtttt)} 2Dy …

Over more than 50 years, intermediate valence states in lanthanide compounds have often
resulted in unexpected or puzzling spectroscopic and magnetic properties. Such …

We report the first bromine-bridged dinuclear [Dy (Cy3PO) 2 (μ-Br)(Br) 2] 2· 2C7H8 single-
molecule magnet with an effective energy barrier of 684 K and magnetic hysteresis below 3 …

We report a family of organometallic rare-earth complexes with the general formula (COT) M
(Cpttt)(where (COT) 2−= cyclooctatetraenide,(Cpttt)−= 1, 2, 4-tri (tert-butyl) …

We report the synthesis and structures of three luminescent dysprosium (III) complexes
based on fluorinated alkoxide ligands of formulas [Dy (L1) 2 (THF) 4][BPh4]· 0.5 THF (1),[Dy …

Partial metathesis between two weakly-coordinating anions in the archetypical dysprosium
metallocene results in the first example of [BPh4]− as a bridging ligand in 4f metals, with a …

The first use of the Schiff base chelate N‐naphthalidene‐o‐aminophenol (naphH2) in Co/Ln
chemistry has afforded a family of isostructural [CoIII2LnIII (OMe) 2 (naph) 2 (O2CMe) 3 …

The π-and σ-basicity of the pyrrolyl ligand affords several coordination modes. A sterically
encumbering coordination sphere around metal centers may foster new coordination modes …