The effect of the electronic structure and flexibility of the counteranions on magnetization relaxation in [Dy (L) 2 (H 2 O) 5] 3+(L= phosphine oxide derivative) …
IF Díaz-Ortega, JM Herrera, S Dey, H Nojiri… - Inorganic Chemistry …, 2020 - pubs.rsc.org
We report here a new DyIII-SIM [Dy (OPCy3) 2 (H2O) 5](CF3SO3) 3· 2OPCy3 (OPCy3=
tricyclohexylphosphine oxide) with a pentagonal bipyramidal geometry, which exhibits a …
tricyclohexylphosphine oxide) with a pentagonal bipyramidal geometry, which exhibits a …
[HTML][HTML] Neutral dicyanidoferrate (II) metalloligands for the rational design of dysprosium (III) single-molecule magnets
M Liberka, M Zychowicz, W Zychowicz… - Chemical …, 2022 - pubs.rsc.org
Diamagnetic cis-dicyanidoferrate (II) complexes bearing blocking aromatic diimines, cis-[FeII
(CN) 2 (LNN) 2] 0 (LNN= 2, 2′-bipyridine, 1, 10′-phenanthroline) serve as metalloligands …
(CN) 2 (LNN) 2] 0 (LNN= 2, 2′-bipyridine, 1, 10′-phenanthroline) serve as metalloligands …
Taming salophen in rare earth metallocene chemistry
E Castellanos, F Benner, S Demir - Inorganic Chemistry Frontiers, 2022 - pubs.rsc.org
A series of multinuclear metallocenes composed of a tBusalophen dianion bound to two rare
earth metal ions, where each is encased in a bis-pentamethylcyclopentadienyl scaffold, was …
earth metal ions, where each is encased in a bis-pentamethylcyclopentadienyl scaffold, was …
Binuclear Lanthanide Complexes Based on 4-Picoline-N-oxide: From Sensitized Luminescence to Single-Molecule Magnet Characteristics
SK Kuppusamy, E Moreno-Pineda… - Crystal Growth & …, 2023 - ACS Publications
Lanthanide complexes featuring luminescent and/or single-molecule magnet (SMM)
characteristic (s) are proposed candidates to develop molecule-based spintronics, memory …
characteristic (s) are proposed candidates to develop molecule-based spintronics, memory …
Air-stable chiral double-decker Dy (III) macrocycles with fluoride ion as the sole axial ligand
X Liu, C Zhao, J Wu, Z Zhu, J Tang - Dalton Transactions, 2022 - pubs.rsc.org
A pair of air-stable double-decker Dy (III) macrocyclic enantiomers featuring sole fluoride
axial ligands were designed and structurally and magnetically characterized. They …
axial ligands were designed and structurally and magnetically characterized. They …
Role of Ab Initio Calculations in the Design and Development of Organometallic Lanthanide‐Based Single‐Molecule Magnets
Single‐molecule magnets based on lanthanides are very attractive due to their potential
applications proposed in the area of microelectronic devices. Very recent advances in this …
applications proposed in the area of microelectronic devices. Very recent advances in this …
Single-Ion Anisotropy and Intramolecular Interactions in CeIII and NdIII Dimers
This article reports the syntheses, characterization, structural description, together with
magnetic and spectroscopic properties of two isostructural molecular magnets based on the …
magnetic and spectroscopic properties of two isostructural molecular magnets based on the …
Single Molecule Magnets
M Giansiracusa, G Gransbury… - … of Inorganic and …, 2021 - research.manchester.ac.uk
Abstract Single-Molecule Magnets (SMMs) are finite molecular species that display slow
relaxation of their magnetisation, equivalent to a magnetic memory effect. Here we give an …
relaxation of their magnetisation, equivalent to a magnetic memory effect. Here we give an …
Synthesis, Crystal Structure, and Magnetization Dynamics of Phenoxy-Bridged Dy2 Complexes with Different Counter Anions and Lattice Solvents
Four phenoxy-bridged Dy2 complexes [Dy2 (L) 2 (H2O) 2](X) 2· solvents [H2L= N, N′-bis (2-
hydroxybenzyl)-N, N′-bis (2-methylpyridyl), X= Br, solvents= 2H2O (1), X= SCN, solvents …
hydroxybenzyl)-N, N′-bis (2-methylpyridyl), X= Br, solvents= 2H2O (1), X= SCN, solvents …
Dysprosium complexes bearing unsupported Dy III–Ge II/Sn II metal–metal bonds as single-ion magnets
SM Chen, J Xiong, YQ Zhang, F Ma, HL Sun… - Chemical …, 2019 - pubs.rsc.org
Two dysprosium complexes bearing unsupported Dy–Ge/Sn metal–metal bonds are
reported here, wherein the Dy–Ge and Dy–Sn bonds both contain relatively large covalency …
reported here, wherein the Dy–Ge and Dy–Sn bonds both contain relatively large covalency …