Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase

ST Stripp, BR Duffus, V Fourmond, C Léger… - Chemical …, 2022 - ACS Publications
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

Medicinal chemistry and biomedical applications of bismuth-based compounds and nanoparticles

DM Griffith, H Li, MV Werrett, PC Andrews… - Chemical Society …, 2021 - pubs.rsc.org
Bismuth as a relatively non-toxic and inexpensive metal with exceptional properties has
numerous biomedical applications. Bismuth-based compounds are used extensively as …

DRAM for distilling microbial metabolism to automate the curation of microbiome function

M Shaffer, MA Borton, BB McGivern… - Nucleic acids …, 2020 - academic.oup.com
Microbial and viral communities transform the chemistry of Earth's ecosystems, yet the
specific reactions catalyzed by these biological engines are hard to decode due to the …

Reviewing the potential of bio-hydrogen production by fermentation

J Baeyens, H Zhang, J Nie, L Appels, R Dewil… - … and Sustainable Energy …, 2020 - Elsevier
Hydrogen is a common reactant in the petro-chemical industry and moreover recognized as
a potential fuel within the next 20 years. The production of hydrogen from biomass and …

Microbial side effects of underground hydrogen storage–Knowledge gaps, risks and opportunities for successful implementation

N Dopffel, S Jansen, J Gerritse - International Journal of Hydrogen Energy, 2021 - Elsevier
As the use of hydrogen gas (H 2) as a renewable energy carrier experiences a major boost,
one of the key challenges for a constant supply is safe and cost-efficient storage of surplus H …

Thousands of microbial genomes shed light on interconnected biogeochemical processes in an aquifer system

K Anantharaman, CT Brown, LA Hug, I Sharon… - Nature …, 2016 - nature.com
The subterranean world hosts up to one-fifth of all biomass, including microbial communities
that drive transformations central to Earth's biogeochemical cycles. However, little is known …

Where silylene–silicon centres matter in the activation of small molecules

C Shan, S Yao, M Driess - Chemical Society Reviews, 2020 - pubs.rsc.org
Small molecules such as H2, N2, CO, NH3, O2 are ubiquitous stable species and their
activation and role in the formation of value-added products are of fundamental importance …

Syntrophy mechanism, microbial population, and process optimization for volatile fatty acids metabolism in anaerobic digestion

Y Zhang, C Li, Z Yuan, R Wang, I Angelidaki… - Chemical Engineering …, 2023 - Elsevier
The low efficiency and stability of anaerobic digestion (AD) has always hindered its wide
application. The accumulation of volatile fatty acids (VFAs) cause acidification and inhibition …

Expanded diversity of microbial groups that shape the dissimilatory sulfur cycle

K Anantharaman, B Hausmann, SP Jungbluth… - The ISME …, 2018 - academic.oup.com
A critical step in the biogeochemical cycle of sulfur on Earth is microbial sulfate reduction,
yet organisms from relatively few lineages have been implicated in this process. Previous …

Hydrogenase enzymes and their synthetic models: the role of metal hydrides

D Schilter, JM Camara, MT Huynh… - Chemical …, 2016 - ACS Publications
Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …