Porous organic cages

X Yang, Z Ullah, JF Stoddart, CT Yavuz - Chemical Reviews, 2023 - ACS Publications
Porous organic cages (POCs) are a relatively new class of low-density crystalline materials
that have emerged as a versatile platform for investigating molecular recognition, gas …

Metal-N-Heterocyclic Carbene Chemistry Directed toward Metallosupramolecular Synthesis and Beyond

S Bai, YF Han - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus As versatile, modular, and strongly coordinating moieties in organometallic
compounds, N-heterocyclic carbenes (NHCs) have led to numerous breakthroughs in …

[HTML][HTML] Polycage membranes for precise molecular separation and catalysis

X Li, W Lin, V Sharma, R Gorecki, M Ghosh… - Nature …, 2023 - nature.com
The evolution of the chemical and pharmaceutical industry requires effective and less
energy-intensive separation technologies. Engineering smart materials at a large scale with …

From Supramolecular Organic Cages to Porous Covalent Organic Frameworks for Enhancing Iodine Adsorption Capability by Fully Exposed Nitrogen‐Rich Sites

K Cheng, H Li, JR Wang, PZ Li, Y Zhao - Small, 2023 - Wiley Online Library
In order to overcome the limitations of supramolecular organic cages for their incomplete
accessibility of active sites in the solid state and uneasy recyclability in liquid solution, herein …

Metallacages and covalent cages for biological imaging and therapeutics

WT Dou, CY Yang, LR Hu, B Song, T Jin… - ACS Materials …, 2023 - ACS Publications
Due to their precise three-dimensional structures and tunable cavities, metallacages and
covalent cages have been widely used in various fields, such as catalysis, separation …

Recent advances in separation membranes based on porous organic molecular materials

S Yu, M Yang, Y Liu, M Liu - Materials Chemistry Frontiers, 2023 - pubs.rsc.org
Membrane separation technology is a highly efficient and energy saving alternative for many
industrial processes. The development of high-performance membrane materials is the …

Picking the lock of coordination cage catalysis

T Piskorz, VM Centelles, R Spicer, F Duarte… - Chemical Science, 2023 - pubs.rsc.org
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …

[HTML][HTML] Cofacial porphyrin organic cages. Metals regulating excitation electron transfer and CO 2 reduction electrocatalytic properties

X Liu, C Liu, X Song, X Ding, H Wang, B Yu, H Liu… - Chemical …, 2023 - pubs.rsc.org
Herein, we introduce a comprehensive study of the photophysical behaviors and CO2
reduction electrocatalytic properties of a series of cofacial porphyrin organic cages (CPOC …

All-inorganic POM cages and their assembly: A review

Q Lai, XX Li, ST Zheng - Coordination Chemistry Reviews, 2023 - Elsevier
Searching for suitable methods to construct all-inorganic cage materials by using
polyoxometalates (POMs) as secondary building units (SBUs) has been of great interest …

Exploring the potential of porous organic cage membranes: Recent advances and applications

T Chen, Y Li, Y Wei, Y Zhang, J Zhu… - Separation and …, 2023 - Elsevier
Porous organic cages (POCs) emerge as a new category of crystalline extended solids—
assembled by discrete organic molecules—featuring cage-shaped architectures and …