Mechanisms and substituent effects of metal-free bioorthogonal reactions

T Deb, J Tu, RM Franzini - Chemical reviews, 2021 - ACS Publications
Reactions that occur under physiological conditions find diverse uses in the chemical and
biological sciences. However, the limitations that biological systems place on chemical …

Knölker Iron Catalysts for Hydrogenation Revisited: A Nonspectator Solvent and Fine-Tuning

M Gimferrer, N Joly, S Escayola, E Viñas… - …, 2022 - ACS Publications
The reductive amination process under hydrogen at high pressure catalyzed by iron
complexes is of great synthetic interest. In this work, we report density functional theory …

Experimental validation of 'pnicogen bonding'in nitrogen by charge density analysis

S Sarkar, MS Pavan, TNG Row - Physical Chemistry Chemical Physics, 2015 - pubs.rsc.org
Experimental validation of ‘pnicogen bonding’ in nitrogen by charge density analysis - Physical
Chemistry Chemical Physics (RSC Publishing) DOI:10.1039/C4CP04690K Royal Society of …

Tetraphenylcyclopentadiene-based conjugated microporous polymers for high-performance energy storage carbons

AF Saber, M Ahmed, SW Kuo, AFM EL-Mahdy - Polymer Chemistry, 2023 - pubs.rsc.org
Conjugated microporous polymers (CMPs) are applied as auspicious electrodes for energy
storage devices. Unfortunately, some synthesized CMPs have low electrical conductivity and …

Metal–Ligand Cooperative C–H Bond Formation by Cyclopentadienone Platinum Complexes

T Higashi, H Ando, S Kusumoto… - Journal of the American …, 2019 - ACS Publications
C–H bond cleavage and formation is one of the most essential elementary reactions in
organic chemistry. Herein, a heterolytic sp3 C–H bond reductive elimination from hydroxyCp …

Source Function applied to experimental densities reveals subtle electron-delocalization effects and appraises their transferability properties in crystals

C Gatti, G Saleh, L Lo Presti - Acta Crystallographica Section B …, 2016 - journals.iucr.org
The Source Function (SF), introduced in 1998 by Richard Bader and Carlo Gatti, is
succinctly reviewed and a number of paradigmatic applications to in vacuo and crystal …

21-Carba-23-oxaporphyrinoids and 21-oxo-21-carba-23-oxaporphyrinoids: macrocyclic π-conjugation involving the carbonyl moiety

A Berlicka, P Foryś-Martowłos, K Hassa… - Organic Chemistry …, 2022 - pubs.rsc.org
A rational synthesis using the carba analogues of tripyrrane and 1, 3-bis (arylhydroxymethyl)
furan as synthons resulted in the formation of 21-carba-23-oxaporphyrin and 21-carba-23 …

[HTML][HTML] Tuning of the electro-optical properties of tetraphenylcyclopentadienone via substitution of oxygen with sterically-hindered electron withdrawing groups

C Coluccini, PT Anusha, HYT Chen, SL Liao, YK Ko… - Scientific reports, 2019 - nature.com
In this report, the substitution of the oxygen group (= O) of Tetraphenylcyclopentadienone
with= CR2 group (R= methyl ester or nitrile) was found to have tuned the electro-optical …

Redox‐Switchable Complexes Based on Nanographene‐NHCs

C Ruiz‐Zambrana, RK Dubey… - … A European Journal, 2022 - Wiley Online Library
A series of rhodium and iridium complexes with a N‐heterocyclic carbene (NHC) ligand
decorated with a perylene‐diimide‐pyrene moiety are described. Electrochemical studies …

Arneroma B: Structure reassignment and total synthesis

NMS Deepak, AG Kutateladze, M Elyashberg… - Tetrahedron, 2023 - Elsevier
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