Microenvironment engineering of single/dual‐atom catalysts for electrocatalytic application

Y Gao, B Liu, D Wang - Advanced Materials, 2023 - Wiley Online Library
Single/dual‐metal atoms supported on carbon matrix can be modulated by coordination
structure and neighboring active sites. Precisely designing the geometric and electronic …

A forward vision for chemodynamic therapy: issues and opportunities

P Zhao, H Li, W Bu - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Since the insight to fuse Fenton chemistry and nanomedicine into cancer therapy, great
signs of progress have been made in the field of chemodynamic therapy (CDT). However …

Generating dual-active species by triple-atom sites through peroxymonosulfate activation for treating micropollutants in complex water

Q Zhou, C Song, P Wang, Z Zhao… - Proceedings of the …, 2023 - National Acad Sciences
The peroxymonosulfate (PMS)-triggered radical and nonradical active species can
synergistically guarantee selectively removing micropollutants in complex wastewater; …

[HTML][HTML] Water decontamination via nonradical process by nanoconfined Fenton-like catalysts

T Liu, S Xiao, N Li, J Chen, X Zhou, Y Qian… - Nature …, 2023 - nature.com
There is an urgent need to develop effective and sustainable solutions to reduce water
pollution. Heterogeneous Fenton-like catalysts are frequently used to eliminate …

A site distance effect induced by reactant molecule matchup in single‐atom catalysts for Fenton‐like reactions

B Wang, C Cheng, M Jin, J He, H Zhang… - Angewandte …, 2022 - Wiley Online Library
Understanding the site interaction nature of single‐atom catalysts (SACs), especially
densely populated SACs, is vital for their application to various catalytic reactions. Herein …

Electron delocalization triggers nonradical Fenton-like catalysis over spinel oxides

ZY Guo, Y Si, WQ Xia, F Wang, HQ Liu… - Proceedings of the …, 2022 - National Acad Sciences
Nonradical Fenton-like catalysis offers opportunities to overcome the low efficiency and
secondary pollution limitations of existing advanced oxidation decontamination …

Multivalent metal catalysts in Fenton/Fenton-like oxidation system: A critical review

Y Liu, J Wang - Chemical Engineering Journal, 2023 - Elsevier
Abstract The Fenton/Fenton-like reaction is an advanced oxidation process, which is widely
recognized for its efficient removal of recalcitrant organic contaminants. In Fenton/Fenton …

Oxygen doping of cobalt-single-atom coordination enhances peroxymonosulfate activation and high-valent cobalt–oxo species formation

QY Wu, ZW Yang, ZW Wang… - Proceedings of the …, 2023 - National Acad Sciences
The high-valent cobalt–oxo species (Co (IV)= O) is being increasingly investigated for water
purification because of its high redox potential, long half-life, and antiinterference properties …

The optimized Fenton-like activity of Fe single-atom sites by Fe atomic clusters–mediated electronic configuration modulation

F Mo, C Song, Q Zhou, W Xue… - Proceedings of the …, 2023 - National Acad Sciences
The performance optimization of isolated atomically dispersed metal active sites is critical
but challenging. Here, TiO2@ Fe species-NC catalysts with Fe atomic clusters (ACs) and …

Generation of FeIV=O and its Contribution to Fenton‐Like Reactions on a Single‐Atom Iron−N−C Catalyst

C Cheng, W Ren, F Miao, X Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Generating FeIV= O on single‐atom catalysts by Fenton‐like reaction has been established
for water treatment; however, the FeIV= O generation pathway and oxidation behavior …