Spin crossover nanomaterials: from fundamental concepts to devices

G Molnár, S Rat, L Salmon, W Nicolazzi… - Advanced …, 2018 - Wiley Online Library
Nanoscale spin crossover materials capable of undergoing reversible switching between
two electronic configurations with markedly different physical properties are excellent …

Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

Computational design of magnetic molecules and their environment using quantum chemistry, machine learning and multiscale simulations

A Lunghi, S Sanvito - Nature Reviews Chemistry, 2022 - nature.com
Having served as a playground for fundamental studies on the physics of d and f electrons
for almost a century, magnetic molecules are now becoming increasingly important for …

Spin‐Crossover Molecules on Surfaces: From Isolated Molecules to Ultrathin Films

L Kipgen, M Bernien, F Tuczek, W Kuch - Advanced Materials, 2021 - Wiley Online Library
Molecular spintronics seeks to use single or few molecules as functional building blocks for
spintronic applications, directly relying on molecular properties or properties of interfaces …

[HTML][HTML] Spin-crossover complexes in direct contact with surfaces

M Gruber, R Berndt - Magnetochemistry, 2020 - mdpi.com
The transfer of the inherent bistability of spin crossover compounds to surfaces has attracted
considerable interest in recent years. The deposition of the complexes on surfaces allows …

Review of Fe-based spin crossover metal complexes in multiscale device architectures

N Amin, SM Said, MFM Salleh, AM Afifi, N Ibrahim… - Inorganica Chimica …, 2023 - Elsevier
Metal complexes involving d 4-d 7 first-row transition metals exhibit spin-crossover (SCO)
behaviour between low-spin and high-spin states in response to external stimuli such as …

Anomalous light‐induced spin‐state switching for iron (II) spin‐crossover molecules in direct contact with metal surfaces

L Zhang, Y Tong, M Kelai, A Bellec… - Angewandte Chemie …, 2020 - Wiley Online Library
Light‐induced spin‐state switching is one of the most attractive properties of spin‐crossover
materials. In bulk, low‐spin (LS) to high‐spin (HS) conversion via the light‐induced excited …

Robust and Selective Switching of an FeIII Spin-Crossover Compound on Cu2N/Cu(100) with Memristance Behavior

T Jasper-Toennies, M Gruber, S Karan, H Jacob… - Nano …, 2017 - ACS Publications
The switching between two spin states makes spin-crossover molecules on surfaces very
attractive for potential applications in molecular spintronics. Using scanning tunneling …

Locking and unlocking the molecular spin crossover transition

X Zhang, PS Costa, J Hooper, DP Miller… - Advanced …, 2017 - Wiley Online Library
The Fe (II) spin crossover complex [Fe {H2B (pz) 2} 2 (bipy)](pz= pyrazol‐1‐yl, bipy= 2, 2′‐
bipyridine) can be locked in a largely low‐spin‐state configuration over a temperature range …

[HTML][HTML] Nonvolatile voltage controlled molecular spin state switching

G Hao, A Mosey, X Jiang, AJ Yost, KR Sapkota… - Applied Physics …, 2019 - pubs.aip.org
Voltage-controlled room temperature isothermal reversible spin crossover switching of [Fe
{H 2 B (pz) 2} 2 (bipy)] thin films is demonstrated. This isothermal switching is evident in thin …