Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Light in gold catalysis

S Witzel, ASK Hashmi, J Xie - Chemical Reviews, 2021 - ACS Publications
Within the wide family of gold-catalyzed reactions, gold photocatalysis intrinsically features
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …

Desulfonylation via radical process: recent developments in organic synthesis

XQ Chu, D Ge, YY Cui, ZL Shen, CJ Li - Chemical reviews, 2021 - ACS Publications
As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …

Desulfonylative transformations of sulfones by transition-metal catalysis, photocatalysis, and organocatalysis

M Nambo, Y Maekawa, CM Crudden - ACS Catalysis, 2022 - ACS Publications
Sulfones are common, readily available reagents that have recently attracted attention as
versatile reagents for cross-coupling reactions. This Review summarizes advances in …

Sulfones as Chemical Chameleons: Versatile Synthetic Equivalents of Small‐Molecule Synthons

BM Trost, CA Kalnmals - Chemistry–A European Journal, 2019 - Wiley Online Library
Sulfones are flexible functional groups that can act as nucleophiles, electrophiles, or even
radicals. Changing the reaction conditions can completely alter the reactivity of a sulfonyl …

Strain-release heteroatom functionalization: development, scope, and stereospecificity

JM Lopchuk, K Fjelbye, Y Kawamata… - Journal of the …, 2017 - ACS Publications
Driven by the ever-increasing pace of drug discovery and the need to push the boundaries
of unexplored chemical space, medicinal chemists are routinely turning to unusual strained …

Synthetic approaches to monofluoroalkenes

G Landelle, M Bergeron, MO Turcotte-Savard… - Chemical Society …, 2011 - pubs.rsc.org
Monofluoroalkenes are an important fluorinated class of compounds with applications in
medicinal chemistry, material sciences and organic chemistry. An overview of methods …

Evolving organic synthesis fostered by the pluripotent phenylsulfone moiety

A El-Awa, MN Noshi, XM du Jourdin… - Chemical reviews, 2009 - ACS Publications
A comprehensive program for the synthesis of natural (or unnatural) products is analogous
to the construction of a pyramid. Careful planning followed by installation of numerous levels …

[HTML][HTML] Dual gold and photoredox catalysis: visible light-mediated intermolecular atom transfer thiosulfonylation of alkenes

H Li, C Shan, CH Tung, Z Xu - Chemical Science, 2017 - pubs.rsc.org
Regioselective difunctionalization of alkenes has attracted significant attention from
synthetic chemists and has the advantage of introducing diverse functional groups into …

Novel dipolarophiles and dipoles in the metal-catalyzed enantioselective 1, 3-dipolar cycloaddition of azomethine ylides

J Adrio, JC Carretero - Chemical communications, 2011 - pubs.rsc.org
The catalytic asymmetric 1, 3-dipolar cycloaddition of azomethine ylides constitutes one of
the most powerful and atom economical methods for the enantioselective construction of …