Light-activated chemical probing of nucleobase solvent accessibility inside cells
The discovery of functional RNAs that are critical for normal and disease physiology
continues to expand at a breakneck pace. Many RNA functions are controlled by the …
continues to expand at a breakneck pace. Many RNA functions are controlled by the …
Dibenzothiophene Sulfoximine as an NH3 Surrogate in the Synthesis of Primary Amines by Copper‐Catalyzed C−X and C−H Bond Amination
Readily accessible dibenzothiophene sulfoximine is an NH3 surrogate allowing the
preparation of free anilines by copper‐catalyzed cross‐coupling reactions with aryl iodides …
preparation of free anilines by copper‐catalyzed cross‐coupling reactions with aryl iodides …
Anodic Dehydrogenative Cyanamidation of Thioethers: Simple and Sustainable Synthesis of N‐Cyanosulfilimines
M Klein, SR Waldvogel - Angewandte Chemie International …, 2021 - Wiley Online Library
A novel and very simple to perform electrochemical approach for the synthesis of several N‐
cyanosulfilimines in good to excellent yields was established. This method provides access …
cyanosulfilimines in good to excellent yields was established. This method provides access …
Photochemistry of azides: the azide/nitrene interface
N Gritsan, M Platz - Organic Azides: Syntheses and …, 2010 - Wiley Online Library
Organic azides are widely used in synthetic organic chemistry. 1–4 An important application
of the photochemistry of organic azides is the photoaffinity labeling of biopolymers. This …
of the photochemistry of organic azides is the photoaffinity labeling of biopolymers. This …
Magnetically bistable nitrenes: Matrix isolation of furoylnitrenes in both singlet and triplet states and triplet 3-furylnitrene
Two simple acylnitrenes, 2-furoylnitrene (2) and 3-furoylnitrene (6), were generated through
266 nm laser photolysis of the corresponding azides. Both are magnetically bistable in …
266 nm laser photolysis of the corresponding azides. Both are magnetically bistable in …
Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium‐Catalysed C− H Amidation
PW Antoni, AV Mackenroth, FF Mulks… - … A European Journal, 2020 - Wiley Online Library
A sulfilimine‐based Group 9 transition‐metal‐catalysed C− H amidation procedure is
reported. Dibenzothiophene‐based sulfilimines were shown to constitute a class of novel …
reported. Dibenzothiophene‐based sulfilimines were shown to constitute a class of novel …
Photochemistry of 2-Naphthoyl Azide. An Ultrafast Time-Resolved UV–Vis and IR Spectroscopic and Computational Study
The photochemistry of 2-naphthoyl azide was studied in various solvents by femtosecond
time-resolved transient absorption spectroscopy with IR and UV–vis detection. The …
time-resolved transient absorption spectroscopy with IR and UV–vis detection. The …
Syntheses of Sulfilimines by Iron-Catalyzed Iminations of Sulfides with 2, 2, 2-Trichloroethyl Sulfamate
K Periasamy, S Gordeeva, C Bolm - The Journal of Organic …, 2024 - ACS Publications
N-protected sulfilimines are prepared by imination of sulfides with a combination of 2, 2, 2-
trichloroethyl sulfamate (H2NTces),(diacetoxyiodo) benzene (PIDA), and a catalytic amount …
trichloroethyl sulfamate (H2NTces),(diacetoxyiodo) benzene (PIDA), and a catalytic amount …
One‐Pot Synthesis of Symmetrical 1, 3‐Diarylureas or Substituted Benzamides Directly from Benzylic Primary Alcohols and Effective Oxidation of Secondary Alcohols …
XQ Li, WK Wang, YX Han… - Advanced Synthesis & …, 2010 - Wiley Online Library
Benzylic primary alcohols can be directly converted into symmetrical 1, 3‐diarylureas or
substituted benzamides via an one‐pot oxidative reaction using the combined reagent of …
substituted benzamides via an one‐pot oxidative reaction using the combined reagent of …
Photochemistry of N-Acetyl-, N-Trifluoroacetyl-, N- Mesyl-, and N-Tosyldibenzothiophene Sulfilimines
V Desikan, Y Liu, JP Toscano… - The Journal of Organic …, 2008 - ACS Publications
Time-resolved infrared (TRIR) spectroscopy, product studies, and computational methods
were applied to the photolysis of sulfilimines derived from dibenzothiophene that were …
were applied to the photolysis of sulfilimines derived from dibenzothiophene that were …