Understanding the unceasing evolution of Co (II) based single-ion magnets

PK Sahu, R Kharel, S Shome, S Goswami… - Coordination Chemistry …, 2023 - Elsevier
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …

Spectroscopic techniques to probe magnetic anisotropy and spin–phonon coupling in metal complexes

AT Hand, BD Watson-Sanders, ZL Xue - Dalton Transactions, 2024 - pubs.rsc.org
Magnetism of molecular quantum materials such as single-molecule magnets (SMMs) has
been actively studied for potential applications in the new generation of high-density data …

Advanced Spectroscopic and Computational Studies of a Cobalt (II) Coordination Polymer with Single-Ion-Magnet Properties

P Tin, AN Bone, NN Bui, YQ Zhang… - The Journal of …, 2022 - ACS Publications
Two-dimensional (2D) coordination polymer (CP)[CoIII (CN) 6] 2 [CoII (TODA)] 3· 7H2O
(TODA= 1, 4, 10-trioxa-7, 13-diazacyclopentadecane, Co-TODA) was reported earlier to …

Field induced single ion magnet behavior in Co II complexes in a distorted square pyramidal geometry

A Dey, J Ali, S Moorthy, JF Gonzalez, F Pointillart… - Dalton …, 2023 - pubs.rsc.org
We report three CoII-based complexes with the general formula [CoII (L)(X) 2] by changing
the halide/pseudo-halide ions [X= NCSe (1SeCN); Cl (2Cl) and Br (3Br)]. The obtained τ5 …

A Single‐Ion Magnet Tape with Five‐Coordinate Cobalt (II) Centers

D Shao, S Moorthy, P Peng, WJ Tang… - European Journal of …, 2022 - Wiley Online Library
Abstract A one‐dimensional (1D) coordination polymer [Co (btca) 1/2 (mbpy)] n (1, mbpy= 4,
4′‐Dimethyl‐2, 2′‐bipyridyl, H4btca= 1, 2, 4, 5‐Benzenetetracarboxylic acid) constructed …

Levamisole based Co (II) Single‐Ion Magnet

S Biswas, L Havlicek, I Nemec, I Salitros… - Chemistry–An Asian …, 2024 - Wiley Online Library
A new Co (II) complex,[Co (NCS) 2 (L) 2](1) has been synthesized based on levamisole (L)
as a new ligand. Single‐crystal X‐ray diffraction analyses confirm that the Co (II) ion is …

Comprehensive Studies of Magnetic Properties of Metal-Organic Frameworks and Molecular Compounds

P Tin - 2023 - trace.tennessee.edu
Single-ion magnets (SIMs) are at the forefront of molecular electronic spin magnets with
potential applications in magnetic memory storage devices. However, the magnetic …

Tetradentate NHC/Thiolato and NHC/Alcoholato Hybrid Scaffolds–A Nickel (II) Complex as Bidentate Metalloligand in 3d Transition Metal Chemistry

G Lococciolo - 2023 - ediss.uni-goettingen.de
The consumption of global primary energy in the last 10 years has grown significantly. Of all
the global primary energy, 87% is provided by fossil fuels and on the other hand, renewable …