Synthesis of bridgehead-azacycles via dual C–N/C–C annulation of α-amino acids, aminals and maleimides
The synthesis of various bridged azacyclic adducts has recently become a reemerging topic
due to their bioactive and natural product mimic profiles. Accordingly, herein, we report a …
due to their bioactive and natural product mimic profiles. Accordingly, herein, we report a …
One-Pot Synthesis of Unprotected 2-Acylpyrroles from 1,2,3-Triazoles and 2-Hydroxymethylallyl Carbonates
JU Park, LZ Huang, HJ Cho, BY Park… - The Journal of Organic …, 2022 - ACS Publications
An efficient, tandem one-pot approach to synthesize multisubstituted 2-acylpyrroles from
readily prepared N-tosyl triazoles and 2-hydroxymethylallyl carbonates is reported. The …
readily prepared N-tosyl triazoles and 2-hydroxymethylallyl carbonates is reported. The …
[PDF][PDF] 银催化下三氟甲基取代的2-咪唑啉化合物的合成
杨明， 黄丹凤， 王克虎， 韩侗育， 赵鹏飞， 王凤… - 有机化学, 2022 - scholar.archive.org
有机化学 Page 1 有机化学 Chinese Journal of Organic Chemistry ARTICLE * Corresponding
authors. E-mail: huangdf@nwnu.edu.cn; huyl@nwnu.edu.cn Received November 4, 2021; …
authors. E-mail: huangdf@nwnu.edu.cn; huyl@nwnu.edu.cn Received November 4, 2021; …
[PDF][PDF] Utilizing the pKa Concept to Address Unfavorable Equilibrium Reactions in the Total Synthesis of Palau'amine
E Ohashi, K Takeuchi, K Tanino… - Modern Natural Product …, 2024 - library.oapen.org
Herein, we introduce the pKa concept as a strategy for proceeding with unfavorable
reactions in the total synthesis of palau'amine. The cascade reaction aimed at constructing …
reactions in the total synthesis of palau'amine. The cascade reaction aimed at constructing …
Fine-Tuning of Acid–Base Equilibria on the Synthesis of the Hexacyclic Core of Palau'amine
Comment: A fragmentation–double cyclization cascade operated within a narrow window of
reactivity. For the required triple deprotonation, stronger bases such as LiHMDS or LDA …
reactivity. For the required triple deprotonation, stronger bases such as LiHMDS or LDA …