Oligomerization Mechanism of Methylglyoxal Regulated by the Methyl Groups in Reduced Nitrogen Species: Implications for Brown Carbon Formation

Q Shi, L Gao, W Li, J Wang, Z Shi, Y Li… - Environmental …, 2024 - ACS Publications
Uncertain chemical mechanisms leading to brown carbon (BrC) formation affect the drivers
of the radiative effects of aerosols in current climate predictions. Herein, the aqueous-phase …

Continuous measurement and molecular compositions of atmospheric water‐soluble brown carbon in the nearshore marine boundary layer of northern China …

H Li, X Qin, J Chen, G Wang, C Liu, D Lu… - Journal of …, 2023 - Wiley Online Library
Understanding the evolution of brown carbon (BrC) in the atmosphere is essential for
investigating its climate effects. This study deployed a novel in‐situ BrC continuous …

Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates

Q Zhao, HB Xie, F Ma, W Nie, C Yan, D Huang… - npj Climate and …, 2023 - nature.com
Organic nitrates are key components of atmospheric organic aerosols. Hydrolysis is one of
their main transformation pathways, affecting atmospheric nitrogen cycle and the properties …

Aqueous-phase chemistry of glyoxal with multifunctional reduced nitrogen compounds: a potential missing route for secondary brown carbon

Y Ji, Z Shi, W Li, J Wang, Q Shi, Y Li… - Atmospheric …, 2024 - acp.copernicus.org
The aqueous-phase chemistry of glyoxal (GL) with reduced nitrogen compounds (RNCs) is
a significant source for secondary brown carbon (SBrC), which is one of the largest …

Heterogeneous chemistry of methyl ethyl ketone on mineral oxide surfaces: impacts of relative humidity and nitrogen dioxide on product formation

E Hettiarachchi, VH Grassian - Environmental Science: Atmospheres, 2023 - pubs.rsc.org
Despite their atmospheric abundance, heterogeneous and multiphase reactions of carbonyl
compounds are poorly understood. In this study, we investigate the surface adsorption and …

Urgency of controlling agricultural nitrogen sources to alleviate summertime air pollution in the North China Plain

R Wang, N Bei, Y Pan, J Wu, S Liu, X Li, J Yu, Q Jiang… - Chemosphere, 2023 - Elsevier
Agricultural nitrogen sources (ANS) have played an increasingly important role in the air
quality since ANS emission controls are much weaker than those for fossil fuel combustion …

Characterization of water-soluble brown carbon chromophores from wildfire plumes in the western USA using size-exclusion chromatography

L Azzarello, RA Washenfelder… - Atmospheric …, 2023 - acp.copernicus.org
Wildfires are an important source of carbonaceous aerosol in the atmosphere. Organic
aerosol that absorbs light in the ultraviolet to visible spectral range is referred to as brown …

Mechanisms of isomerization and hydration reactions of typical β-diketone at the air-droplet interface

Y Ji, W Luo, Q Shi, X Ma, Z Wu, W Zhang, Y Gao… - Journal of Environmental …, 2024 - Elsevier
Acetylacetone (AcAc) is a typical class of β-diketones with broad industrial applications due
to the property of the keto-enol isomers, but its isomerization and chemical reactions at the …

[引用][C] The catalytic role of the solvent in the ammonization of glyoxal and acetaldehyde

VP Tuguldurova, AV Kotov, AV Fateev - 2023 - elibrary.ru

[引用][C] Enactment from water-soluble maroon carbon chromophores from wildfire plumes in the west USA using size-exclusion chromatography

L Azzarello, BA Washenfelder, MA Robinson…