A porous cobalt (II)–organic framework exhibiting high room temperature proton conductivity and field-induced slow magnetic relaxation

Y Zhou, S Moorthy, XQ Wei, SK Singh, Z Tian… - Dalton …, 2023 - pubs.rsc.org
A two-dimensional (2D) cobalt (II) metal–organic framework (MOF) constructed by a ditopic
organic ligand, formulated as {[Co (Hbic)(H2O)]· 4H2O} n (1)(H2bic= 1H-benzimidazole-5 …

Structure-property correlation in stabilizing axial magnetic anisotropy in octahedral Co (II) complexes

S Tripathi, S Vaidya, N Ahmed, EA Klahn, H Cao… - Cell Reports Physical …, 2021 - cell.com
Stabilizing an easy axis of magnetization in an octahedral Co (II) complex is an extremely
challenging task, which is evident from reports that more than 90% possess easy-plane …

A molecular tetrahedral cobalt–seleno-based complex as an efficient electrocatalyst for water splitting

IM Abdullahi, J Masud, PC Ioannou, E Ferentinos… - Molecules, 2021 - mdpi.com
The cobalt–seleno-based coordination complex,[Co {(SePiPr2) 2N} 2], is reported with
respect to its catalytic activity in oxygen evolution and hydrogen evolution reactions (OER …

The rationalized pathway from field-induced slow magnetic relaxation in Co II–W IV chains to single-chain magnetism in isotopological Co II–WV analogues

T Charytanowicz, R Jankowski, M Zychowicz… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Single-chain magnets (SCMs) and single-molecule magnets (SMMs), and their sub-class of
single-ion magnets (SIMs) exhibit slow relaxation of magnetization leading to the magnetic …

Field-induced single-ion magnet based on a quasi-octahedral Co (II) complex with mixed sulfur–oxygen coordination environment

DV Korchagin, YE Gureev, EA Yureva, GV Shilov… - Dalton …, 2021 - pubs.rsc.org
Synthesis and characterization of structure and magnetic properties of the quasi-octahedral
complex (pipH2)[Co (TDA) 2] 2H2O (I),(pipH22+= piperazine dication, TDA2−= thiodiacetic …

Diastereotopic groups in two new single-enantiomer structures (R2) P (O)[NH-(+) CH (C2H5)(C6H5)](R= OC6H5 and C6H5)

F Eslami, M Pourayoubi, F Sabbaghi… - Structure …, 2023 - journals.iucr.org
The crystal structures of two single-enantiomer compounds, ie diphenyl [(R)-(+)-α-
ethylbenzylamido] phosphate, C21H22NO3P or (C6H5O) 2P (O)[NH-(R)-(+) CH …

Field‐Induced Slow Magnetization Relaxation of a Tetrahedral S= 2 FeIIS4‐Containing Complex

M Pissas, E Ferentinos, P Kyritsis, Y Sanakis - ChemPlusChem, 2024 - Wiley Online Library
In the work described herein, the spin relaxation properties of the mononuclear tetrahedral
S= 2 [Fe {(SPiPr2) 2N} 2] complex (1) were studied by employing static and dynamic …

Field-induced Co (II) single-ion magnet in octahedral [S6] coordination environment

Y Zhou, RZ Yao, X Cai, Z Wang, P Cen, Y Yang… - Journal of Molecular …, 2023 - Elsevier
The soft donor ligands are of great importance to the pursuit of 3d transition-metal
complexes with large magnetic anisotropy. Herein, a soft tripodal ligand, hydrotris …

Electronic properties of the S= 5/2 Mn (II) complexes [Mn {PhC (O) NP (O) PPh2}(N, N)(NO3)],(N, N)= phenanthroline, neocuproine, 2, 2′-bipyridine

K Nano, G Zahariou, PC Ioannou, MM Alam… - Polyhedron, 2021 - Elsevier
The synthesis, as well as the structural and electronic properties of the [Mn (O, O)(N, N)(NO
3)] complexes,(O, O)={PhC (O) NP (O) PPh 2}−,(N, N)= phenanthroline (1), neocuproine (2) …

A systematic study of the influence of ligand field on the slow magnetic dynamics of Co (ii)-diimine compounds

I Bhowmick, BS Newell, MP Shores - Dalton Transactions, 2021 - pubs.rsc.org
Herein we report heteroleptic Co (II) diimine complexes [Co (H2bip) 2Cl2](1),[Co (H2bip)
2Br2](2),[Co (H2bip) 3] Br2· 1MeOH (3) and [Co (H2bip) 2 (Me2bpy)] Br2·(MeCN) 0.5·(H2O) …