A review of functional linear carbon chains (oligoynes, polyynes, cumulenes) and their applications as molecular wires in molecular electronics and optoelectronics

MR Bryce - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
Linear, sp-hybridised, 1-dimensional (1D) all-carbon wires are conceptually the simplest π-
conjugated organic molecules. Their fundamental experimental and theoretical properties …

Structural chirality and electronic chirality in quantum materials

B Yan - Annual Review of Materials Research, 2024 - annualreviews.org
In chemistry and biochemistry, chirality represents the structural asymmetry characterized by
nonsuperimposable mirror images for a material such as DNA. In physics, however, chirality …

Real-time monitoring of reaction stereochemistry through single-molecule observations of chirality-induced spin selectivity

C Yang, Y Li, S Zhou, Y Guo, C Jia, Z Liu, KN Houk… - Nature Chemistry, 2023 - nature.com
Stereochemistry has an essential role in organic synthesis, biological catalysis and physical
processes. In situ chirality identification and asymmetric synthesis are non-trivial tasks …

Spinterface origin for the chirality-induced spin-selectivity effect

S Alwan, Y Dubi - Journal of the American Chemical Society, 2021 - ACS Publications
When electrons are injected through a chiral molecule, the resulting current may become
spin polarized. This effect, known as the chirality-induced spin-selectivity (CISS) effect, has …

Highly conducting single-molecule topological insulators based on mono-and di-radical cations

L Li, JZ Low, J Wilhelm, G Liao, S Gunasekaran… - Nature Chemistry, 2022 - nature.com
Single-molecule topological insulators are promising candidates as conducting wires over
nanometre length scales. A key advantage is their ability to exhibit quasi-metallic transport …

Roadmap on quantum nanotechnologies

A Laucht, F Hohls, N Ubbelohde… - …, 2021 - iopscience.iop.org
Quantum phenomena are typically observable at length and time scales smaller than those
of our everyday experience, often involving individual particles or excitations. The past few …

Intermolecular and Electrode-Molecule Bonding in a Single Dimer Junction of Naphthalenethiol as Revealed by Surface-Enhanced Raman Scattering Combined with …

K Homma, S Kaneko, K Tsukagoshi… - Journal of the American …, 2023 - ACS Publications
Electron transport through noncovalent interaction is of fundamental and practical
importance in nanomaterials and nanodevices. Recent single-molecule studies employing …

Highly nonlinear transport across single-molecule junctions via destructive quantum interference

JE Greenwald, J Cameron, NJ Findlay, T Fu… - Nature …, 2021 - nature.com
To rival the performance of modern integrated circuits, single-molecule devices must be
designed to exhibit extremely nonlinear current–voltage (I–V) characteristics,,–. A common …

Mechanically tunable quantum interference in ferrocene-based single-molecule junctions

M Camarasa-Gómez, D Hernangómez-Pérez… - Nano Letters, 2020 - ACS Publications
Ferrocenes are ubiquitous organometallic building blocks that comprise a Fe atom
sandwiched between two cyclopentadienyl (Cp) rings that rotate freely at room temperature …

Electronic spin separation induced by nuclear motion near conical intersections

Y Wu, JE Subotnik - Nature communications, 2021 - nature.com
Though the concept of Berry force was proposed thirty years ago, little is known about the
practical consequences of this force as far as chemical dynamics are concerned. Here, we …