Asymmetric Cross-Coupling of Aldehydes with Diverse Carbonyl or Iminyl Compounds by Photoredox-Mediated Cobalt Catalysis

Z Chi, JB Liao, X Cheng, Z Ye, W Yuan… - Journal of the …, 2024 - ACS Publications
The asymmetric cross-coupling of unsaturated bonds, hampered by their comparable
polarity and reactivity, as well as the scarcity of efficient catalytic systems capable of …

Chiral Osmium(II)/Salox Species Enabled Enantioselective γ‐C(sp3)−H Amidation: Integrated Experimental and Computational Validation For the Ligand Design and …

W Chen, H Xu, FX Liu, K Chen… - Angewandte Chemie …, 2024 - Wiley Online Library
Herein, multiple types of chiral Os (II) complexes have been designed to address the
appealing yet challenging asymmetric C (sp3)− H functionalization, among which the Os …

Double Catalytic Activity Unveiled: Synthesis, Characterization, and Catalytic Applications of Iridium Complexes in Transfer Hydrogenation and Photomediated …

L Blanco, A Uroz, K Gutiérrez, S Cabrera… - ACS …, 2024 - ACS Publications
Iridium complexes have been demonstrated to be highly active catalysts for a wide variety of
transformations. Their unique photophysical and photochemical properties render them as …

Synthesis of δ-Lactams via Biomimetic Polycyclization Initiated by an Iridium Acylnitrenoid Transfer

M Oestreich, HFT Klare, D Brösamlen - Synfacts, 2024 - thieme-connect.com
Significance: Chang, Zanoni and co-workers report a stereoselective iridium acylnitrenoid-
initiated biomimetic cascade cyclization to access polycyclic-lactams. This mild protocol …