A hitchhiker's guide to click-chemistry with nucleic acids

NZ Fantoni, AH El-Sagheer, T Brown - Chemical Reviews, 2021 - ACS Publications
Click chemistry is an immensely powerful technique for the fast and efficient covalent
conjugation of molecular entities. Its broad scope has positively impacted on multiple …

Supramolecular fluorescent sensors: An historical overview and update

C Guo, AC Sedgwick, T Hirao, JL Sessler - Coordination chemistry reviews, 2021 - Elsevier
Since as early as 1867, molecular sensors have been recognized as being intelligent
“devices” capable of addressing a variety of issues related to our environment and health …

A catalysis-driven artificial molecular pump

S Amano, SDP Fielden, DA Leigh - Nature, 2021 - nature.com
All biological pumps are autonomous catalysts; they maintain the out-of-equilibrium
conditions of the cell by harnessing the energy released from their catalytic decomposition of …

Controlling catalyst activity, chemoselectivity and stereoselectivity with the mechanical bond

AW Heard, JM Suárez, SM Goldup - Nature Reviews Chemistry, 2022 - nature.com
Mechanically interlocked molecules, such as rotaxanes and catenanes, are receiving
increased attention as scaffolds for the development of new catalysts, driven by both their …

Emerging applications of carbon nanohoops

EJ Leonhardt, R Jasti - Nature Reviews Chemistry, 2019 - nature.com
A cycloparaphenylene can be thought of as the shortest possible cross section of an
armchair carbon nanotube. Although envisioned decades ago, these molecules—also …

Sigma-hole interactions in anion recognition

JYC Lim, PD Beer - Chem, 2018 - cell.com
Sigma (σ)-holes are electron-deficient regions that arise from the anisotropic distribution of
electron density on the atom of group 14 (tetrels), 15 (pnictogens), 16 (chalcogens), and 17 …

Active template strategy for the preparation of π-conjugated interlocked nanocarbons

JH May, JM Van Raden, RL Maust, LN Zakharov… - Nature Chemistry, 2023 - nature.com
Mechanically interlocked carbon nanostructures represent a relatively unexplored frontier in
carbon nanoscience due to the difficulty in preparing these unusual topological materials …

Chirality in rotaxanes and catenanes

EMG Jamieson, F Modicom, SM Goldup - Chemical Society Reviews, 2018 - pubs.rsc.org
Although chiral mechanically interlocked molecules (MIMs) have been synthesised and
studied, enantiopure examples are relatively under-represented in the pantheon of reported …

Halogen bonding motifs for anion recognition

J Pancholi, PD Beer - Coordination Chemistry Reviews, 2020 - Elsevier
The halogen bond is a powerful non-covalent interaction between the electron deficient
sigma-hole region of a group 17 halogen element covalently bonded to electron …

Simplicity in the design, operation, and applications of mechanically interlocked molecular machines

AW Heard, SM Goldup - ACS Central Science, 2020 - ACS Publications
Mechanically interlocked molecules are perhaps best known as components of molecular
machines, a view further reinforced by the Nobel Prize in 2016 to Stoddart and Sauvage …