[HTML][HTML] Production of O radicals from cavitation bubbles under ultrasound
K Yasui - Molecules, 2022 - mdpi.com
In the present review, the production of O radicals (oxygen atoms) in acoustic cavitation is
focused. According to numerical simulations of chemical reactions inside a bubble using an …
focused. According to numerical simulations of chemical reactions inside a bubble using an …
[HTML][HTML] On a heavy path–determining cold plasma-derived short-lived species chemistry using isotopic labelling
Cold atmospheric plasmas (CAPs) are promising medical tools and are currently applied in
dermatology and epithelial cancers. While understanding of the biomedical effects is already …
dermatology and epithelial cancers. While understanding of the biomedical effects is already …
Chemoselective Oxidation of Thiols with Oxoammonium Cations
SM Weierbach, RP Reynolds… - The Journal of …, 2022 - ACS Publications
The oxidation of various aryl and aliphatic thiols with the commercially available and
environmentally benign reagent Bobbitt's salt (1) has been investigated. The reaction affords …
environmentally benign reagent Bobbitt's salt (1) has been investigated. The reaction affords …
Pyridazine N-Oxides as Photoactivatable Surrogates for Reactive Oxygen Species
VS Basistyi, JH Frederich - Organic letters, 2022 - ACS Publications
A method for the photoinduced evolution of atomic oxygen from pyridazine N-oxides was
developed. This underexplored oxygen allotrope mediates arene C–H oxidation within …
developed. This underexplored oxygen allotrope mediates arene C–H oxidation within …
Photochemistry of N‐Phenyl Dibenzothiophene Sulfoximine†
A Isor, R Hommelsheim, GW Cone… - Photochemistry and …, 2021 - Wiley Online Library
Sulfoximines are popular scaffolds in drug discovery due to their hydrogen bonding
properties and chemical stability. In recent years, the role of reactive intermediates such as …
properties and chemical stability. In recent years, the role of reactive intermediates such as …
Evidence for diffusing atomic oxygen uncovered by separating reactants with a semi-permeable nanocapsule barrier
SM Omlid, SA Dergunov, A Isor, KL Sulkowski… - Chemical …, 2019 - pubs.rsc.org
Ground-state atomic oxygen [O (3P)] is an oxidant whose formation in solution was
proposed but never proven. Polymer nanocapsules were used to physically separate …
proposed but never proven. Polymer nanocapsules were used to physically separate …
[HTML][HTML] Identifying cysteine residues susceptible to oxidation by photoactivatable atomic oxygen precursors using a proteome-wide analysis
A Isor, BV Chartier, M Abo, ER Currens… - RSC Chemical …, 2021 - pubs.rsc.org
The reactivity profile of atomic oxygen [O (3P)] in the condensed phase has shown a
preference for the thiol group of cysteines. In this work, water-soluble O (3P)-precursors …
preference for the thiol group of cysteines. In this work, water-soluble O (3P)-precursors …
Photodeoxygenation of phenanthro[4,5-bcd]thiophene S-oxide, triphenyleno[1,12-bcd]thiophene S-oxide and perylo[1,12-bcd]thiophene S-oxide
SM Chintala, JT Petroff II, A Barnes… - Journal of Sulfur …, 2019 - Taylor & Francis
Sulfoxides, upon irradiation with ultraviolet (UV) light undergo α-cleavage, hydrogen
abstraction, photodeoxygenation, bimolecular photoreduction, and stereo-mutation. The UV …
abstraction, photodeoxygenation, bimolecular photoreduction, and stereo-mutation. The UV …
Insights into the Mechanism of O(3P)-Mediated Oxidation of Alkenes through Kinetic Isotope Effects and Computational Modeling
PF Maness, RD McCulla - The Journal of Organic Chemistry, 2024 - ACS Publications
Photodeoxygenation of aryl sulfoxides, such as dibenzothiophene S-oxide (DBTO),
produces atomic oxygen [O (3P)] in solution. The mechanism of alkene oxidation with O (3P) …
produces atomic oxygen [O (3P)] in solution. The mechanism of alkene oxidation with O (3P) …
The unexpected effect of ferrocenyl substituents on the photochemistry of dianthryl sulfoxides
N Removski, MO Wolf - Chemical Communications, 2023 - pubs.rsc.org
Photoexcitation of ferrocenyl substituted dianthryl sulfoxide results in photochemical reaction
products that differ from all known compounds of this class. This is enabled by energy …
products that differ from all known compounds of this class. This is enabled by energy …