Intrinsic viscosity and dielectric relaxation of ring polymers in dilute solutions

S Kumar, P Biswas - The Journal of Chemical Physics, 2023 - pubs.aip.org
The absence of chain ends makes ring polymers distinctly different from their linear
analogues. The intrinsic viscosity, complex viscosity and the dielectric relaxation of ring …

Reactivity of B (C6F5) 3 towards glycidol: The formation of branched cyclic polyglycidol structures

MA Al Assiri, EG Urreizti, CA Pagnacco… - European Polymer …, 2022 - Elsevier
Abstract B (C 6 F 5) 3 is a strong electrophilic catalyst that promote the ring-opening
polymerization of a number of epoxides via the formation of zwitterionic growing chains …

In Vitro Biocompatibility and Endothelial Permeability of Branched Polyglycidols Generated by Ring-Opening Polymerization of Glycidol with B(C6F5)3 under Dry …

CA Pagnacco, MH Kravicz, FS Sica… - …, 2024 - ACS Publications
Polyglycidol or polyglycerol (PG), a polyether widely used in biomedical applications, has
not been extensively studied in its branched cyclic form (bc PG), despite extensive research …

MALDI-ToF MS Study of Macrocyclic Polyethers Generated by Electrophilic Zwitterionic Ring Expansion Polymerization of Monosubstituted Epoxides with B(C6F5)3

FM Haque, CM Schexnayder, JM Matxain… - …, 2019 - ACS Publications
The electrophilic zwitterionic ring expansion polymerization of monosubstituted epoxides
initiated by tris (pentafluorophenyl) borane [B (C6F5) 3] is investigated to reveal the effect of …

An insight into the anionic ring-opening polymerization with tetrabutylammonium azide for the generation of pure cyclic poly (glycidyl phenyl ether)

J Ochs, A Veloso, DE Martínez-Tong, A Alegria… - …, 2018 - ACS Publications
We evaluate the use of tetrabutylammonium azide (N3NBu4) as an anionic ring-opening
polymerization initiator for synthesizing azide-terminated linear poly (glycidyl phenyl ether) …

Understanding zwitterionic ring‐expansion polymerization through mass spectrometry

M Ahmad, SM Grayson - Mass Spectrometry Reviews, 2024 - Wiley Online Library
Zwitterionic ring‐expansion polymerization (ZREP) is a polymerization method in which a
cyclic monomer is converted into a cyclic polymer through a zwitterionic intermediate. In this …

Synthesis of a cyclic poly (methyl acrylate) via topological transformation of a [1] rotaxane

K Nakazono, T Ogawa, T Takata - Materials Chemistry Frontiers, 2019 - pubs.rsc.org
Even today, obtaining a cyclic polymer in pure form remains difficult. This paper discloses a
synthetic protocol for a vinyl polymer-type cyclic polymer in pure form. A linear …

[PDF][PDF] Materials Today Chemistry

EG Urreizti, X Gastearena, A Lam… - Materials …, 2024 - researchgate.net
The synthesis of polyglycidol (or polyglycerol) using tris-(pentafluorophenyl) borane [B
(C6F5) 3] as a catalyst produces a branched structure with a cyclic core by a mechanism of …

Separation, identification, and confirmation of cyclic and tadpole macromolecules via UPLC-MS/MS

JM O'Neill, J Mao, FM Haque, F Barroso-Bujans… - Analyst, 2022 - pubs.rsc.org
Macrocyclic poly (glycidyl phenyl ether)(pGPE) synthesized via zwitterionic ring opening
polymerization is typically contaminated by chains with linear and tadpole architecture …

Kinetic differences in the intercalation of linear and cyclic penta (ethylene oxide) s into graphite oxide leading to separation by topology

F Barroso-Bujans, A Alegria - Physical Chemistry Chemical Physics, 2017 - pubs.rsc.org
In the present study, the structural differences between linear and cyclic oligo (ethylene
oxide) s are demonstrated to cause large kinetic differences in the intercalation of both …