Two-dimensional polymers and polymerizations

AM Evans, MJ Strauss, AR Corcos, Z Hirani… - Chemical …, 2021 - ACS Publications
Synthetic chemists have developed robust methods to synthesize discrete molecules, linear
and branched polymers, and disordered cross-linked networks. However, two-dimensional …

Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

Engineering of robust topological quantum phases in graphene nanoribbons

O Gröning, S Wang, X Yao, CA Pignedoli… - Nature, 2018 - nature.com
Boundaries between distinct topological phases of matter support robust, yet exotic quantum
states such as spin–momentum locked transport channels or Majorana fermions,–. The idea …

On-surface synthesis of graphene nanostructures with π-magnetism

S Song, J Su, M Telychko, J Li, G Li, Y Li… - Chemical Society …, 2021 - pubs.rsc.org
Graphene nanostructures (GNs) including graphene nanoribbons and nanoflakes have
attracted tremendous interest in the field of chemistry and materials science due to their …

Carbon-based nanostructures as a versatile platform for tunable π-magnetism

DG de Oteyza, T Frederiksen - Journal of Physics: Condensed …, 2022 - iopscience.iop.org
Emergence of π-magnetism in open-shell nanographenes has been theoretically predicted
decades ago but their experimental characterization was elusive due to the strong chemical …

Atomic force microscopy for molecular structure elucidation

L Gross, B Schuler, N Pavliček… - Angewandte Chemie …, 2018 - Wiley Online Library
Using scanning probe microscopy techniques, at low temperatures and in ultrahigh vacuum,
individual molecules adsorbed on surfaces can be probed with ultrahigh resolution to …

Tailoring topological order and π-conjugation to engineer quasi-metallic polymers

B Cirera, A Sánchez-Grande, B De la Torre… - Nature …, 2020 - nature.com
Topological band theory predicts that a topological electronic phase transition between two
insulators must proceed via closure of the electronic gap. Here, we use this transition to …

On‐Surface Synthesis of Edge‐Extended Zigzag Graphene Nanoribbons

A Kinikar, X Xu, MD Giovannantonio… - Advanced …, 2023 - Wiley Online Library
Graphene nanoribbons (GNRs) have gained significant attention in nanoelectronics due to
their potential for precise tuning of electronic properties through variations in edge structure …

On-surface polyarylene synthesis by cycloaromatization of isopropyl substituents

A Kinikar, M Di Giovannantonio, JI Urgel, K Eimre… - Nature …, 2022 - nature.com
Immobilization of organic molecules on metal surfaces and their coupling via thermally
induced C–C bond formation is an important technique in organic and polymer synthesis …

Unusual stabilization of larger acenes and heteroacenes

M Müller, L Ahrens, V Brosius, J Freudenberg… - Journal of Materials …, 2019 - pubs.rsc.org
The larger acenes and heteroacenes (> pentacenes) are attractive, yet sensitive materials;
several strategies were developed to stabilize such species.“Classic” approaches employ …