The creation of a 1s core hole in a 3d transition metal ion gives rise to an emission spectrum
that can be recorded using a crystal analyzer. K shell X-ray spectroscopy using an analyser …

Formation of stable iron hydrides on more nucleophilic (electron-rich) metal centers than
those found in hydrogenases with CO ligands would inhibit or at least slow down function …

This Handbook on Metalloproteins focuses on the available structural information of proteins
and their metal ion coordination spheres. It centers on the metal ions indispensable for life …

The recent X-ray crystal structure determinations of several hydrogenase enzymes have
engaged the organometallic community owing to the presence of CN− and CO ligands …

A series of dinuclear complexes,(μ-SRS) Fe2 (CO) 6 (R=− CH2CH2−,− CH2CH2CH2−,−
CH2− C6H4− CH2−; edt, pdt, and o-xyldt, respectively) has been examined for specific …

Infrared-spectroscopic studies on the [NiFe]-hydrogenase of Chromatium vinosum-enriched
in 15 N or 13 C, as well as chemical analyses, show that this enzyme contains three non …

The carbon monoxide complex of [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F
has been characterized by X-ray crystallography and absorption and resonance Raman …

The heterogeneous complexity of sludges and wastewaters has created gross uncertainty
and deviations in predictions of suitable models for their measurement. At the same time, it is …

The nickel− iron hydrogenase from Chromatium vinosum adsorbs at a pyrolytic graphite
edge-plane (PGE) electrode and catalyzes rapid interconversion of H+ (aq) and H2 at …

During the era of prebiotic evolution, which culminated in the appearance of cellular life
forms, the earth had a reducing atmosphere. Fueled by volcanic activity and by magmatic …