Recent Advances in Electron Donor‐Acceptor (EDA)‐Complex Reactions involving Quaternary Pyridinium Derivatives

B Saxena, RI Patel, A Sharma - Advanced Synthesis & …, 2023 - Wiley Online Library
Quaternary pyridinium compounds are valuable intermediates in organic synthesis, which
have gained immense popularity in the synthetic community. The application of transition …

Visible light-assisted chemistry of vinyl azides and its applications in organic synthesis

B Saxena, RI Patel, J Tripathi, A Sharma - Organic & Biomolecular …, 2023 - pubs.rsc.org
Vinyl azides have emerged as highly versatile precursors in organic synthesis due to their
rich reactivity driven by the excellent leaving-group ability of molecular nitrogen. Over the …

Visible Light Induced EDA‐mediated Deaminative C‐2 Alkylation of Heterocyclic‐N‐Oxides using Katritzky salts

N Singh, S Sharma, A Sharma - Advanced Synthesis & …, 2023 - Wiley Online Library
Herein, a direct C‐2 alkylation of Heterocyclic‐N‐oxides with alkyl amines as Katritzky salts
via visible‐light induced deaminative approach was developed. Mechanistic studies …

The Application of Sulfonyl Hydrazides in Electrosynthesis: A Review of Recent Studies

BC Qian, CZ Zhu, GB Shen - ACS omega, 2022 - ACS Publications
Sulfonyl hydrazides are viewed as alternatives to sulfinic acids and their salts or sulfonyl
halides, which are broadly used in organic synthesis or work as active pharmaceutical …

Phosphonium Salt-Promoted C2–H Functionalization of Heterocyclic N-Oxides

Q Ma, Y Shi, D Wang - Organic Letters, 2023 - ACS Publications
We report the development of a phosphonium salt as a remarkable activating agent that
enables the direct conversion of C2–H bonds of a variety of heterocyclic N-oxides into C2 …

Ts2O Promoted Deoxygenative C–H Dithiocarbonation of Quinoline N-Oxides with Potassium O-Alkyl Xanthates

MY Zhao, JJ Tang, YJ Lin, ZY Tian… - The Journal of Organic …, 2024 - ACS Publications
A simple, efficient, and practical method for the synthesis of S-quinolyl xanthates was
developed via Ts2O-promoted deoxygenative C–H dithiocarbonation of quinoline N-oxides …

Ts 2 O mediated deoxygenative C2-dithiocarbamation of quinoline N-oxides with CS 2 and amines

LY Xie, C Liu, SY Wang, ZY Tian, S Peng - RSC advances, 2024 - pubs.rsc.org
A general, efficient and practical protocol for Ts2O promoted deoxygenative
dithiocarbamation of quinoline N-oxides with in situ generated dithiocarbamic acids from …

Synthesis of Quinoline-2-thiones by Selective Deoxygenative CH/CS Functionalization of Quinoline N-Oxides with Thiourea

DI Bugaenko, OA Tikhanova… - The Journal of Organic …, 2023 - ACS Publications
Quinoline-2-thiones valuable for synthetic and medicinal chemistry applications were
obtained with excellent regioselectivity employing a deoxygenative C–H functionalization of …

TsCl promoted deoxygenative phosphorothiolation of quinoline N-oxides towards S-quinolyl phosphorothioates

LY Wu, T Huang, ZY Tian, XQ Xu, S Peng… - Organic & Biomolecular …, 2024 - pubs.rsc.org
A convenient, efficient and practical approach for the synthesis of S-quinolyl
phosphorothioates via cheap TsCl promoted deoxygenative C2–H phosphorothiolation of …

Green and fast 2-aryloxylation/amination of quinolines

C Bu, K Wang, C Gong, D Wang - Green Chemistry, 2024 - pubs.rsc.org
A rapid, efficient and eco-friendly synthesis of 2-aroxyquinolines and 2-aminoquinolines was
developed respectively through activating agent-promoted deoxygenative aryloxylation …