Redox-tag processes: Intramolecular electron transfer and its broad relationship to redox reactions in general

Y Okada, K Chiba - Chemical reviews, 2017 - ACS Publications
Explosive growth in the use of open shell reactivity, including neutral radicals and radical
ions, in the field of synthetic organic chemistry has been observed in the past decade …

Potential energy surface crossings and the mechanistic spectrum for intramolecular electron transfer in organic radical cations

L Blancafort, F Jolibois, M Olivucci… - Journal of the American …, 2001 - ACS Publications
The structure of the potential energy surface for the intramolecular electron transfer (IET) of
four different model radical cations has been determined by using reaction path mapping …

Radical‐type reactivity and catalysis by single‐electron transfer to or from redox‐active ligands

JI van der Vlugt - Chemistry–A European Journal, 2019 - Wiley Online Library
Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Synthetic molecular photoelectrochemistry: new frontiers in synthetic applications, mechanistic insights and scalability

S Wu, J Kaur, TA Karl, X Tian… - Angewandte Chemie …, 2022 - Wiley Online Library
Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for
the generation and handling of reactive intermediates. PEC permits selective single …

New redox strategies in organic synthesis by means of electrochemistry and photochemistry

J Liu, L Lu, D Wood, S Lin - ACS Central Science, 2020 - ACS Publications
As the breadth of radical chemistry grows, new means to promote and regulate single-
electron redox activities play increasingly important roles in driving modern synthetic …

Single electron transfer in radical ion and radical-mediated organic, materials and polymer synthesis

N Zhang, SR Samanta, BM Rosen, V Percec - Chemical Reviews, 2014 - ACS Publications
The mechanisms of most organic reactions are considered to proceed by two-electron
transfer pathways, even though both biology and radical chemistry rely extensively on one …

Oxidation leading to reduction: redox‐induced electron transfer (RIET)

JS Miller, KS Min - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Complex electron transfer reactions have been characterized whereby in addition to
electron transfer, subsequent electrochemical, chemical and even in some cases biological …

Understanding reactivity patterns of radical cations

M Schmittel, A Burghart - Angewandte Chemie International …, 1997 - Wiley Online Library
Over the last 15 years electron transfer activation has emerged as a valuable concept for
accomplishing novel reactions and has found widespread application in the selective …

Evolution of neutral organic super-electron-donors and their applications

E Doni, JA Murphy - Chemical Communications, 2014 - pubs.rsc.org
In recent times, metal-free chemistry has received significant attention due to its inherent
qualities and its potential savings in the costs of (i) reagents and (ii) environmental …

Charge transfer reactions along a supramolecular redox gradient

A Mateo-Alonso, C Ehli, DM Guldi… - Journal of the American …, 2008 - ACS Publications
Charge Transfer Reactions along a Supramolecular Redox Gradient | Journal of the
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