Transition‐metal‐catalyzed radical reactions are becoming increasingly important in modern
organic chemistry. They offer fascinating and unconventional ways for connecting molecular …

Direct difunctionalization of simple alkenes, the incorporation of two functional groups onto a
carbon–carbon double bond, is of particular interest to the chemical community owing to its …

Transition metal-catalysed allylic functionalization reactions have been established as a
central synthetic transformation to enable the construction of carbon–carbon and carbon …

Recent years have witnessed remarkable advances in radical reactions involving main‐
group metal complexes. This includes the isolation and detailed characterization of main …

Radical reactions play an important role in modern organic synthetic chemistry. The
generation of carbon radicals from the homolytic cleavage of carbon–metal bonds has been …

In recent years, radical‐mediated transformations of organohalides, a class of powerful
chemical transformations, have become an important field at the forefront of organic …

Two named reactions of fundamental importance and paramount utility in organic synthesis
have been reinvestigated, the Barton decarboxylation and Giese radical conjugate addition …

Two‐component Giese type radical additions are highly practical and established reactions.
Herein, three‐component radical conjugate additions of unactivated alkenes to Michael …

Welcome to radical catalysis: Radicals are tamed in transition-metal complexes which serve
as catalysts for a number of reactions-Kumada couplings (see scheme), highly …

Saturated carbonyl compounds, such as aldehydes and esters, are basic building blocks for
the synthesis of organic molecules and materials. Reactions with carbonyl compounds as …