Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

The mixed-ligand complex [Ni (dppp)(PPh2NBz2)](BF4) 2, 3,(where PPh2NBz2 is 1, 5-
dibenzyl-3, 7-diphenyl-1, 5-diaza-3, 7-diphosphacyclooctane and dppp is 1, 3-bis …

Conspectus Sustainable, carbon-neutral energy is needed to supplant the worldwide
reliance on fossil fuels in order to address the persistent problem of increasing emissions of …

The iron complexes CpFe (PPh2NBn2) Cl (1-Cl), CpFe (PPh2NPh2) Cl (2-Cl), and CpFe
(PPh2C5) Cl (3-Cl)(where PPh2NBn2 is 1, 5-dibenzyl-1, 5-diaza-3, 7-diphenyl-3, 7 …

A bis-diphosphine nickel complex with tert-butyl functionalized pendant amines [Ni (PCy2Nt-
Bu2) 2] 2+ has been synthesized. It is a highly active electrocatalyst for the oxidation of …

Described are new derivatives of the type [HNiFe (SR) 2 (diphosphine)(CO) 3]+, which
feature a Ni (diphosphine) group linked to a Fe (CO) 3 group by two bridging thiolate …

A series of Ni-based electrocatalysts,[Ni (7PPh2NC6H4X) 2](BF4) 2, featuring seven-
membered cyclic diphosphine ligands incorporating a single amine base, 1-para-X-phenyl …

Highly efficient electrocatalysts for both hydrogen evolution and hydrogen oxidation have
been designed, synthesized, and characterized. The catalysts in their resting states are air …

Conspectus Sustainable processes that utilize nontoxic, readily available, and inexpensive
starting materials for organic synthesis constitute a major objective in modern chemical …

We present the results of a comprehensive theoretical investigation of the role of pendant
amine ligands in the oxidation of H2 and formation of H2 by [Ni (PR2NR′ 2) 2] 2+ …