Oxygen tolerance of a molecular engineered cathode for hydrogen evolution based on a cobalt diimine–dioxime catalyst

N Kaeffer, A Morozan, V Artero - The Journal of Physical Chemistry …, 2015 - ACS Publications
We report here that a bioinspired cobalt diimine–dioxime molecular catalyst for hydrogen
evolution immobilized onto carbon nanotube electrodes proves tolerant toward oxygen. The …

Molecular engineering of a cobalt-based electrocatalytic nanomaterial for H2 evolution under fully aqueous conditions

ES Andreiadis, PA Jacques, PD Tran, A Leyris… - Nature …, 2013 - nature.com
The viability of a hydrogen economy depends on the design of efficient catalytic systems
based on earth-abundant elements. Innovative breakthroughs for hydrogen evolution based …

Hydrogen evolution catalyzed by cobalt diimine–dioxime complexes

N Kaeffer, M Chavarot-Kerlidou… - Accounts of chemical …, 2015 - ACS Publications
Conspectus Mimicking photosynthesis and producing solar fuels is an appealing way to
store the huge amount of renewable energy from the sun in a durable and sustainable way …

The dark side of molecular catalysis: diimine–dioxime cobalt complexes are not the actual hydrogen evolution electrocatalyst in acidic aqueous solutions

N Kaeffer, A Morozan, J Fize, E Martinez, L Guetaz… - ACS …, 2016 - ACS Publications
The perspective of integrating molecular catalysts for hydrogen evolution into operating
devices requires the benchmarking of their activity preferentially in aqueous media. Within a …

Highly selective oxygen reduction to hydrogen peroxide on transition metal single atom coordination

K Jiang, S Back, AJ Akey, C Xia, Y Hu, W Liang… - Nature …, 2019 - nature.com
Shifting electrochemical oxygen reduction towards 2e–pathway to hydrogen peroxide
(H2O2), instead of the traditional 4e–to water, becomes increasingly important as a green …

Molecular engineered nanomaterials for catalytic hydrogen evolution and oxidation

N Coutard, N Kaeffer, V Artero - Chemical Communications, 2016 - pubs.rsc.org
The active sites of hydrogenases have inspired the design of molecular catalysts for
hydrogen evolution and oxidation. In this feature article, we showcase key elements of bio …

A Poly(cobaloxime)/Carbon Nanotube Electrode: Freestanding Buckypaper with Polymer‐Enhanced H2‐Evolution Performance

B Reuillard, J Warnan, JJ Leung… - Angewandte …, 2016 - Wiley Online Library
A freestanding H2‐evolution electrode consisting of a copolymer‐embedded cobaloxime
integrated into a multiwall carbon nanotube matrix by π–π interactions is reported. This …

Carbon nanotubes with cobalt corroles for hydrogen and oxygen evolution in pH 0–14 solutions

X Li, H Lei, J Liu, X Zhao, S Ding… - Angewandte Chemie …, 2018 - Wiley Online Library
Water splitting is promising to realize a hydrogen‐based society. The practical use of
molecular water‐splitting catalysts relies on their integration onto electrode materials. We …

A flexible electrode based on Al-doped nickel hydroxide wrapped around a carbon nanotube forest for efficient oxygen evolution

F Malara, S Carallo, E Rotunno, L Lazzarini… - ACS …, 2017 - ACS Publications
The development of highly active, cheap, and stable electrocatalysts for overall water
splitting is strategic for industrial electrolysis processes aiming to achieve sustainable …

Cathodic electrochemical activation of Co 3 O 4 nanoarrays: a smart strategy to significantly boost the hydrogen evolution activity

L Yang, H Zhou, X Qin, X Guo, G Cui… - Chemical …, 2018 - pubs.rsc.org
Co (hydro) oxides show unsatisfactory catalytic activity for the hydrogen evolution reaction
(HER) in alkaline media, and it is thus highly desirable but still remains a challenge to …