Aggregation‐Induced Emission and Circularly Polarized Luminescence Duality in Tetracationic Binaphthyl‐Based Cyclophanes
Here, we report an approach to the synthesis of highly charged enantiopure cyclophanes by
the insertion of axially chiral enantiomeric binaphthyl fluorophores into the constitutions of …
the insertion of axially chiral enantiomeric binaphthyl fluorophores into the constitutions of …
Intramolecular energy and solvent‐dependent chirality transfer within a BINOL‐perylene hetero‐cyclophane
G Ouyang, J Rühe, Y Zhang, MJ Lin, M Liu… - Angewandte …, 2022 - Wiley Online Library
Multichromophoric macrocycles and cyclophanes are important supramolecular
architectures for the elucidation of interchromophoric interactions originating from precise …
architectures for the elucidation of interchromophoric interactions originating from precise …
Compact CPL emitters based on a [2.2] paracyclophane scaffold: recent developments and future perspectives
Due to their unique three-dimensional framework and intriguing electronic properties,[2.2]
paracyclophanes (pCps) have been employed over the years as building blocks in materials …
paracyclophanes (pCps) have been employed over the years as building blocks in materials …
Conformational Dynamics of Monomer‐versus Dimer‐like Features in a Naphthalenediimide‐Based Conjugated Cyclophane
The design and synthesis of an enantiomeric pair of 1, 8‐diethynylanthracene‐bridged
naphthalenediimide (NDI)‐based cyclophanes (Cyclo‐NDIs) are reported. Each enantiomer …
naphthalenediimide (NDI)‐based cyclophanes (Cyclo‐NDIs) are reported. Each enantiomer …
Planar chiral tetrasubstituted [2.2] paracyclophane: optical resolution and functionalization
Y Morisaki, M Gon, T Sasamori… - Journal of the …, 2014 - ACS Publications
We achieved optical resolution of 4, 7, 12, 15-tetrasubstituted [2.2] paracyclophane and
subsequent transformation to planar chiral building blocks. An optically active propeller …
subsequent transformation to planar chiral building blocks. An optically active propeller …
From the Decks to the Bridges: Optoelectronics in [2.2] paracyclophane Chemistry
E Elacqua, LR MacGillivray - European Journal of Organic …, 2010 - Wiley Online Library
In this microreview, we highlight optical properties of [2.2] paracyclophanes (pCps). We
demonstrate how the spectroscopic properties that stem from the strained and π‐stacked …
demonstrate how the spectroscopic properties that stem from the strained and π‐stacked …
Polycationic Open‐Shell Cyclophanes: Synthesis of Electron‐Rich Chiral Macrocycles, and Redox‐Dependent Electronic States
Y Shi, C Li, J Di, Y Xue, Y Jia, J Duan, X Hu… - Angewandte …, 2024 - Wiley Online Library
π‐Conjugated chiral nanorings with intriguing electronic structures and chiroptical
properties have attracted considerable interests in synthetic chemistry and materials …
properties have attracted considerable interests in synthetic chemistry and materials …
Chiral TPE Foldamers in Macrocycles: Aggregation Enhanced Emission and Circularly Polarized Luminescence
Y Wang, L Cui, Y Wang, F Li, Y Li… - Chemistry–A European …, 2023 - Wiley Online Library
Chiral macrocycles with circularly polarized luminescence (CPL) have attracted increasing
attention due to the rigid structure, symmetrical chiral geometry and large luminescence …
attention due to the rigid structure, symmetrical chiral geometry and large luminescence …
Synthesis of highly twisted, nonplanar aromatic macrocycles enabled by an axially chiral 4, 5-diphenylphenanthrene building block
The synthesis, structures, and properties of highly twisted, nonplanar aromatic macrocycles
are described. These macrocycles with an approximately 90° twist angle were synthesized …
are described. These macrocycles with an approximately 90° twist angle were synthesized …
Mechanoresponsive luminescence and liquid-crystalline behaviour of a cyclophane featuring two 1, 6-bis (phenylethynyl) pyrene groups
Cyclophanes have been attractive targets over recent decades because of their fascinating
molecular structures and inherent ability to act as supramolecular hosts. However …
molecular structures and inherent ability to act as supramolecular hosts. However …