Charge separation by creating band bending in metal–organic frameworks for improved photocatalytic hydrogen evolution

C Zhang, C Xie, Y Gao, X Tao, C Ding… - Angewandte …, 2022 - Wiley Online Library
Metal–organic frameworks (MOFs) have been intensively studied as a class of
semiconductor‐like materials in photocatalysis. However, band bending, which plays a …

Highly stable phosphonate‐based MOFs with engineered bandgaps for efficient photocatalytic hydrogen production

YP Zhu, J Yin, E Abou‐Hamad, X Liu… - Advanced …, 2020 - Wiley Online Library
Photoactive metal–organic frameworks (MOFs) represent one of the most promising
materials for photocatalytic hydrogen production, but phosphonate‐based MOFs have …

Boosting photocatalytic hydrogen production of a metal–organic framework decorated with platinum nanoparticles: the platinum location matters

JD Xiao, Q Shang, Y Xiong, Q Zhang… - Angewandte Chemie …, 2016 - Wiley Online Library
Improving the efficiency of electron–hole separation and charge‐carrier utilization plays a
central role in photocatalysis. Herein, Pt nanoparticles of ca. 3 nm are incorporated inside or …

Enhanced visible-light-driven hydrogen production through MOF/MOF heterojunctions

S Kampouri, FM Ebrahim, M Fumanal… - … Applied Materials & …, 2021 - ACS Publications
A strategy for enhancing the photocatalytic performance of MOF-based systems (MOF: metal–
organic framework) is developed through the construction of MOF/MOF heterojunctions. The …

Design of metal-organic framework-based photocatalysts for hydrogen generation

S Liu, C Zhang, Y Sun, Q Chen, L He, K Zhang… - Coordination Chemistry …, 2020 - Elsevier
Metal-organic framework (MOF) materials are suitable for photocatalytic hydrogen
production reactions due to their tunable structure, modifiable pores and a large number of …

Incorporating transition‐metal phosphides into metal‐organic frameworks for enhanced photocatalysis

K Sun, M Liu, J Pei, D Li, C Ding, K Wu… - Angewandte …, 2020 - Wiley Online Library
Metal‐organic frameworks (MOFs) have been shown to be an excellent platform in
photocatalysis. However, to suppress electron–hole recombination, a Pt cocatalyst is usually …

Photogenerated hole traps in metal-organic-framework photocatalysts for visible-light-driven hydrogen evolution

Z Lian, Z Li, F Wu, Y Zhong, Y Liu, W Wang… - Communications …, 2022 - nature.com
Efficient electron-hole separation and carrier utilization are key factors in photocatalytic
systems. Here, we use a metal-organic framework (NH2-UiO-66) modified with inner …

Manipulating metal oxidation state over ultrastable metal-organic frameworks for boosting photocatalysis

YN Gong, JH Mei, JW Liu, HH Huang, JH Zhang… - Applied Catalysis B …, 2021 - Elsevier
The development of efficient and stable photocatalysts in drastic conditions is highly
desirable yet remains challenging. Herein, we report an exceptionally stable cerium metal …

Metal–organic framework-derived heterojunctions as nanocatalysts for photocatalytic hydrogen production

L Lu, B Wu, W Shi, P Cheng - Inorganic Chemistry Frontiers, 2019 - pubs.rsc.org
Based on various well-defined components and structures, high specific surface areas and
adjustable pore sizes, metal–organic frameworks (MOFs) have not only been widely used …

Enhancing Built‐in Electric Fields for Efficient Photocatalytic Hydrogen Evolution by Encapsulating C60 Fullerene into Zirconium‐Based Metal‐Organic Frameworks

L Liu, H Meng, Y Chai, X Chen, J Xu, X Liu… - Angewandte …, 2023 - Wiley Online Library
High‐efficiency photocatalysts based on metal‐organic frameworks (MOFs) are often limited
by poor charge separation and slow charge‐transfer kinetics. Herein, a novel MOF …