Poly (Butylene Succinate) Molar Mass Calculation by GPC and 1H‐NMR

VC da Costa, ERF dos Santos… - Macromolecular …, 2021 - Wiley Online Library
The determination of the molar mass of a polymer is a fundamental characterization. One of
the most common techniques used for this purpose is gel permeation chromatography …

[PDF][PDF] Solution viscosity–molar mass relationships for poly (butylene succinate) and discussion on molar mass analysis

Q Charlier, E Girard, F Freyermouth… - Express Polym …, 2015 - academia.edu
Solution viscosity – molar mass relationships for poly(butylene succinate) and discussion on
molar mass analysis Page 1 1. Introduction Poly(butylene succinate) (PBS) is one of the ‘old’ …

A new method for estimation of viscosity‐average molecular weight of polymers from GPC

HK Mahabadi - Journal of Polymer Science: Polymer Physics …, 1984 - Wiley Online Library
A novel approach for the determination of the viscosity‐average molecular weight of
polymers for which Mark–Houwink constants are not known is presented. This method can …

Polymer characterization methods

G Montaudo, MS Montaudo - Mass Spectrometry of Polymers, 2001 - api.taylorfrancis.com
Polymers can display a variety of structures, including linear, cyclic, and branched chains,
copolymers in which different repeat units are aligned along the chain in different manners …

Preparation and characterization of high molecular weight poly (butylene succinate)

YK Han, SR Kim, J Kim - Macromolecular Research, 2002 - Springer
Abstract Poly (butylene succinate)(PBS) prepolymers were prepared by the condensation
polymerization of 1, 4-butanediol (1, 4-BD) and succinic acid (SCA) in the presence of …

The kinetics of poly (butylene succinate) synthesis and the influence of molar mass on its thermal properties

M Garin, L Tighzert, I Vroman… - Journal of Applied …, 2014 - Wiley Online Library
The synthesis of poly (butylene succinate)(PBS) of Mw ranging from 4000 to 180,000 g mol−
1 is realized with molar ratios [COOH] 0/[OH] 0 of 1 and 0.98, and varying amounts of …

Absolute Mn Determined by Gel Permeation Chromatography—Differential Viscometry

JM Goldwasser - 1993 - ACS Publications
A new method has been developed to quantitatively determine the number average
molecular weight (Mn) of a polymer sample by GPC using an online differential viscometer …

Molar mass determination via linear regression from SEC measurements: The case of polylactide, polycaprolactone and poly (2, 2‐dimethylthrimethylene carbonate)

B Kost, M Socka, K Cichoń, M Brzeziński… - Polymers for …, 2024 - Wiley Online Library
Molar mass correction coefficients (cc) were determined for calculating the absolute molar
masses of polylactide (PLA), polycaprolactone (PCL), and poly (2, 2‐dimethyltrimethylene …

Comparison of number–average molecular weights calculated by GPC and membrane osmometry

MR Ambler, RD Mate - Journal of Polymer Science Part A‐1 …, 1972 - Wiley Online Library
Data are presented which show that when a polymer contains an appreciable amount of low
molecular weight species below the diffusion limit of the osmometer membrane, the osmotic …

Using spectroscopy with chemometrics to measure polymer molar mass

MJ Shenton, H Herman, GC Stevens - Polymer international, 2000 - Wiley Online Library
The ability to determine the molar mass of a polymer is of fundamental importance to
describe polymer molecular characteristics. Conventional methods for measuring molar …