Atomically dispersed rhodium on self-assembled phosphotungstic acid: structural features and catalytic CO oxidation properties

B Zhang, H Asakura, N Yan - Industrial & Engineering Chemistry …, 2017 - ACS Publications
Atomically dispersed Rh catalysts supported on phosphotungstic acid (PTA) with Rh loading
up to 0.9 wt% were prepared through a self-assembly method. Rh stays exclusively as …

CO oxidation on the phosphotungstic acid supported Rh single–atom catalysts via Rh–assisted Mans–van Krevelen mechanism

LL Zhang, MJ Sun, CG Liu - Molecular Catalysis, 2019 - Elsevier
Recently, there are contradictory picture of the surface processes for polyoxometalates
(POMs) supported single–atom catalysts (SACs) in CO oxidation, both Langmuir …

In situ spectroscopy-guided engineering of rhodium single-atom catalysts for CO oxidation

MJ Hülsey, B Zhang, Z Ma, H Asakura, DA Do… - Nature …, 2019 - nature.com
Single-atom catalysts have recently been applied in many applications such as CO
oxidation. Experimental in situ investigations into this reaction, however, are limited. Hereby …

Bifunctionally faceted Pt/Ru nanoparticles for preferential oxidation of CO in H2

X Du, Y Lang, K Cao, J Yang, J Cai, B Shan, R Chen - Journal of Catalysis, 2021 - Elsevier
Global hydrogen production from catalytic reforming of hydrocarbons exceeds 50 million
tons annually and accounts for 2–5% of global energy consumption. The hydrogen product …

Active Site Design in a Core–Shell Nanostructured Catalyst for a One‐Pot Oxidation Reaction

S Okada, K Mori, T Kamegawa, M Che… - … A European Journal, 2011 - Wiley Online Library
Hydrogen peroxide (H2O2) is not only an environmentally friendly oxidizing agent, but also
a highly selective oxidant used in the manufacturing of numerous organic and inorganic …

The role of surface oxygenated-species and adsorbed hydrogen in the oxygen reduction reaction (ORR) mechanism and product selectivity on Pd-based catalysts in …

R Rahul, RK Singh, B Bera… - Physical Chemistry …, 2015 - pubs.rsc.org
Oxygen reduction reaction (ORR) is investigated on bulk PdO-based catalysts (oxides of Pd
and Pd3Co) in oxygen-saturated 0.1 M HClO4 to establish the role of surface oxides and …

Unusual Redox Behavior of Rh/AlPO4 and Its Impact on Three-Way Catalysis

M Machida, S Minami, S Hinokuma… - The Journal of …, 2015 - ACS Publications
The influence of the redox behavior of Rh/AlPO4 on automotive three-way catalysis (TWC)
was studied to correlate catalytic activity with thermal stability and metal–support …

Rhodium metal–rhodium oxide (Rh–Rh 2 O 3) nanostructures with Pt-like or better activity towards hydrogen evolution and oxidation reactions (HER, HOR) in acid …

MK Kundu, R Mishra, T Bhowmik… - Journal of Materials …, 2018 - pubs.rsc.org
Design and synthesis of HER/HOR catalysts are of crucial importance for the development of
polymer fuel cells and water electrolyzers. We report the synthesis of Rh–Rh2O3 …

Highly active subnano Rh/Fe (OH) x catalyst for preferential oxidation of CO in H2-rich stream

H Guan, J Lin, L Li, X Wang, T Zhang - Applied Catalysis B: Environmental, 2016 - Elsevier
A novel catalyst formulation of 3.1 wt.% Rh/Fe (OH) x was prepared via a co-precipitation
method and investigated for CO preferential oxidation in H 2-rich stream. This catalyst …

New insights into the role of the electronic properties of oxide promoters in Rh-catalyzed selective synthesis of oxygenates from synthesis gas

G Prieto, P Concepción, A Martínez, E Mendoza - Journal of catalysis, 2011 - Elsevier
Abstract A series of 2.5% Rh/M@ Al 2 O 3 model catalysts were prepared by supporting Rh
on high-area γ-Al 2 O 3, resulting in a surface covered by a monolayer (4.5–7 atoms/nm 2) of …