Photolysis of N-benzoyl-S, S-diphenylsulfilimine or N-benzoyl dibenzothiophene sulfilimine
produces PhNCO and also benzoylnitrene. Direct observation of the triplet nitrene, energetic …

Time-resolved infrared (TRIR) spectroscopy, product studies, and computational methods
were applied to the photolysis of sulfilimines derived from dibenzothiophene that were …

To evaluate the ability of dibenzothiophene N-substituted sulfilimines as photochemical
nitrene sources, their photolyses in the presence of several trapping reagents, such as …

New sulfoximine-and phenanthrene-based photochemical precursors to oxynitrenes have
been developed. These precursors have been used to examine the chemistry and …

N-Ethyloxycarbonyl-S, S-dibenzothiphene sulfilimine and Nt-butyloxycarbonyl-S, S-
dibenzothiphene sulfilimine have been utilized as precursors to ethoxycarbonylnitrene and t …

Photolysis of β-azido propiophenone derivatives, 1, with built-in sensitizer units, leads to
selective formation of triplet alkyl nitrenes 2 that were detected directly with laser flash …

The photochemistry of 2-naphthoyl azide was studied in various solvents by femtosecond
time-resolved transient absorption spectroscopy with IR and UV–vis detection. The …

Several 1-and 2-substituted thianthrene sulfilimine derivatives were prepared and the
selectivity toward oxidation and N-tosylimination under several conditions was studied. In …

Sulfoximines are popular scaffolds in drug discovery due to their hydrogen bonding
properties and chemical stability. In recent years, the role of reactive intermediates such as …

The photodecomposition of a pyrazolyl substituted p-nitrophenyl azide has been studied as
an intramolecular model for the reactivity of the parent azide, largely used for photochemical …