Innovation of hydrocarbon oxidation with molecular oxygen and related reactions

Y Ishii, S Sakaguchi, T Iwahama - Advanced Synthesis & …, 2001 - Wiley Online Library
An innovation of the aerobic oxidation of hydrocarbons through catalytic carbon radical
generation under mild conditions was achieved by using N‐hydroxyphthalimide (NHPI) as a …

Alkane Oxidation with Molecular Oxygen Using a New Efficient Catalytic System:  N-Hydroxyphthalimide (NHPI) Combined with Co(acac)n (n = 2 or 3)

Y Ishii, T Iwahama, S Sakaguchi… - The Journal of …, 1996 - ACS Publications
A novel class of catalysts for alkane oxidation with molecular oxygen was examined. N-
Hydroxyphthalimide (NHPI) combined with Co (acac) n (n= 2 or 3) was found to be an …

Recent progress in aerobic oxidation of hydrocarbons by N-hydroxyimides

Y Ishii, S Sakaguchi - Catalysis today, 2006 - Elsevier
Innovative carbon radical generation from hydrocarbons through a catalytic process under
mild conditions has been achieved by the use of N-hydroxyphthalimide (NHPI) as a catalyst …

Preparation of Hydroperoxides by N‐Hydroxyphthalimide‐Catalyzed Aerobic Oxidation of Alkylbenzenes and Hydroaromatic Compounds and Its Application

O Fukuda, S Sakaguchi, Y Ishii - Advanced Synthesis & …, 2001 - Wiley Online Library
An efficient approach to phenols and aldehydes through the formation of hydroperoxides
from alkylbenzenes was successfully achieved by aerobic oxidation using N …

A new strategy for alkane oxidation with O2 using N‐hydroxyphthalimide (NHPI) as a radical catalyst

Y Ishii, S Sakaguchi - Catalysis Surveys from Asia, 1999 - Springer
A practical catalytic method to convert alkanes into the corresponding oxygen‐containing
compounds with O 2 under mild conditions using N‐hydroxyphthalimide (NHPI) in the …

Catalytic Oxidation of Alkylbenzenes with Molecular Oxygen under Normal Pressure and Temperature by N-Hydroxyphthalimide Combined with Co(OAc)2

Y Yoshino, Y Hayashi, T Iwahama… - The Journal of …, 1997 - ACS Publications
A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic
acids under atmospheric dioxygen at ambient temperature using a combined catalytic …

Efficient Oxidation of Alcohols to Carbonyl Compounds with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide Combined with a Co Species

T Iwahama, Y Yoshino, T Keitoku… - The Journal of …, 2000 - ACS Publications
Highly efficient catalytic oxidation of alcohols with molecular oxygen by N-
hydroxyphthalimide (NHPI) combined with a Co species was developed. The oxidation of 2 …

Metal-free, NHPI catalyzed oxidative cleavage of C–C double bond using molecular oxygen as oxidant

R Lin, F Chen, N Jiao - Organic letters, 2012 - ACS Publications
A metal-free N-hydroxyphthalimide (NHPI) catalyzed aerobic oxidative cleavage of olefins
has been developed. Molecular oxygen is used as the oxidant and reagent for this …

Organocatalytic oxidations mediated by nitroxyl radicals

RA Sheldon, IWCE Arends - Advanced Synthesis & Catalysis, 2004 - Wiley Online Library
The use of nitroxyl radicals, alone or in combination with transition metals, as catalysts in
oxidation processes is reviewed from both a synthetic and a mechanistic viewpoint. Two …

Aerobic oxidation of alcohols to carbonyl compounds catalyzed by n-hydroxyphthalimide (NHPI) combined with Co (acac) 3

T Iwahama, S Sakaguchi, Y Nishiyama, Y Ishii - Tetrahedron Letters, 1995 - Elsevier
Aerobic oxidation of various alcohols has been accomplished by using a new catalytic
system, N-hydroxyphthalimide (NHPI) combined with Co (acac) 3. The oxidation of alcohols …